7. All of the following statements concerning ligand field theory are true EXCEPT A. in low-spin complexes, electrons are concentrated in the day, dys, and du orbitals. B. in an isolated atom or ion, the five d orbitals have identical energy. C. low-spin complexes contain the maximum number of unpaired electrons. D. the crystal field splitting is larger in low-spin complexes than high-spin complexes. E. the energy difference between d orbitals often corresponds to an energy of visible light.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 73QRT
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Question
Cr(aq) + 3 e
Cr(s)
Zn²(aq) + 2 e → Zn(s)
2 H₂O() +2 e → H₂(g) + 2 OH(aq)
Mn2(aq) + 2 e
A(an) + 3 e
Mn(s)
Al(s)
7. All of the following statements concerning ligand field theory are true EXCEPT
A. in low-spin complexes, electrons are concentrated in the day, dys, and dr
orbitals.
B. in an isolated atom or ion, the five d orbitals have identical energy.
C. low-spin complexes contain the maximum number of unpaired electrons.
D. the crystal field splitting is larger in low-spin complexes than high-spin
complexes.
E. the energy difference between d orbitals often corresponds to an energy of
visible light.
8. All of the following complexes will be colored (in the visible) EXCEPT
A. [Co(en)]2+
B. [Fe(CN)6]
C. [Ni(H₂O)]²+
D. [Cd(NH3)4]2+
9. A positron has a mass number of
a(n)
a. 0; 1+; proton
b.
1; 2+; proton
c. 0; 1+; electron
d. 1; 2+; electron
e. 0; 0; proton
-0.76
-0.83
-1.18
-1.66
a. [Cr(CO)6]C13
b. [Cu(OH)4(NH3)2]
c. K4[Mn(CN)6]
d. [Pt(en)3] (NO3)4
e. [Pt(NH3)2(OH₂)CIJ3PO4
10. In which one of the following is the oxidation number of the transition metal incorrect?
Complex Species
Oxidation Number of Transition Metal
+3
, a charge of
a. 0.57 V
b. 0.61 V
c. 0.74 V
d. 0.66 V
e. 0.68 V
+4
+3
+4
+2
and a mass equal to that of
11. Consider the following reaction: If a galvanic cell utilizes this reaction and the initial
concentrations are [Hg22+] = 0.10 M, [Sn²+] = 0.30 M, and [Sn] = 0.20 M, what will be
Ecell under these conditions?
Hg₂+ (aq) + Sn²+ (aq) → Sn(aq) + 2Hg(1)
3
-ELECTRONIC SCENFIC
888
AUTO POWER OF
hyp
E
EXP
Transcribed Image Text:Cr(aq) + 3 e Cr(s) Zn²(aq) + 2 e → Zn(s) 2 H₂O() +2 e → H₂(g) + 2 OH(aq) Mn2(aq) + 2 e A(an) + 3 e Mn(s) Al(s) 7. All of the following statements concerning ligand field theory are true EXCEPT A. in low-spin complexes, electrons are concentrated in the day, dys, and dr orbitals. B. in an isolated atom or ion, the five d orbitals have identical energy. C. low-spin complexes contain the maximum number of unpaired electrons. D. the crystal field splitting is larger in low-spin complexes than high-spin complexes. E. the energy difference between d orbitals often corresponds to an energy of visible light. 8. All of the following complexes will be colored (in the visible) EXCEPT A. [Co(en)]2+ B. [Fe(CN)6] C. [Ni(H₂O)]²+ D. [Cd(NH3)4]2+ 9. A positron has a mass number of a(n) a. 0; 1+; proton b. 1; 2+; proton c. 0; 1+; electron d. 1; 2+; electron e. 0; 0; proton -0.76 -0.83 -1.18 -1.66 a. [Cr(CO)6]C13 b. [Cu(OH)4(NH3)2] c. K4[Mn(CN)6] d. [Pt(en)3] (NO3)4 e. [Pt(NH3)2(OH₂)CIJ3PO4 10. In which one of the following is the oxidation number of the transition metal incorrect? Complex Species Oxidation Number of Transition Metal +3 , a charge of a. 0.57 V b. 0.61 V c. 0.74 V d. 0.66 V e. 0.68 V +4 +3 +4 +2 and a mass equal to that of 11. Consider the following reaction: If a galvanic cell utilizes this reaction and the initial concentrations are [Hg22+] = 0.10 M, [Sn²+] = 0.30 M, and [Sn] = 0.20 M, what will be Ecell under these conditions? Hg₂+ (aq) + Sn²+ (aq) → Sn(aq) + 2Hg(1) 3 -ELECTRONIC SCENFIC 888 AUTO POWER OF hyp E EXP
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