Complete the reaction predicting the products: Name all functional groups for reactants/Products, Sketch/Name allreactants/Products using IUPAC rules, and determine if each reaction is Reversible or Non - Reversible. Classify product ifpossible as a ketal/acetal/hemi - ketal/hemi-acetal a. e. b. acid chloride and alcohol (non-reversible) Ester withhalogen Propyl 2-chlorobutanoate c. heptanoic acid, + ethanol larrd. butyl butanoate + NaOH → e. hexylethanoate + NaOHN-011 uster strong base (non-reversible) (Or 1-hydroxyhexane) i need help with A, C, D, E

The objective of the question is to predict the products of the given reactions, name all functional…

Answered: Complete the reaction predicting the…

EBK A SMALL SCALE APPROACH TO ORGANIC L

4th Edition

ISBN:9781305446021

Author:Lampman

Publisher:Lampman

Chapter89: Thin-layer Chromatography

Section: Chapter Questions

Problem 8P

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TRUE OR FALSE 15.In Fehling’s test, the theoretical product after an aldehyde is mixed with Fehling’s solution is alcohol. 16.Iodoform, which has a molecular formula of CH3I, is indicative that ketomethyl group is prresent. 17.Based on the physical property, hydroquinone has a lower boiling point compared to catechol. 18.When FeCl3 is used in visualizing aspirin in tin layer chromatography, the resulting spot is in red color.
When synthesizing acetals and ketals, what is the main driving force behind whether the reaction favors the carbonyl species or the acetal/ketal? a the catalytic acid b solvent c temperature d Le Châtelier's Principle
1. Write the skeletal structures of propanal, acetone and cyclohexanone. What is the major intermolecular force (IMF) found in them? Based on their major intermolecular force and molecular weight, what can you predict on their solubility in water? Chemical Name Skeletal Structures Major IMF Solubility in water Propanal Acetone Cyclohexanone 2. What is the purpose of Tollens’ test (Part B)? What is the evidence of a positive result? 3. What is the purpose of oxidation test (Part C)? What is the evidence of a positive result?
4. draw the structure of the organic product for each alcohol reacting with permanganate. Look on the internet for an explanation of why the tertiary alcohol in presence of KMnO4 might react. (hint may involve dehydration.) - methanol - ethanol - propanol - 2-methyl-2-propanol
Observe the REACTION in the diagram below to answer questions 1. What is the type of hybridization of the carboxyl carbon in the mechanism? a. sp1.5b. sp3c. sp2d. sp 2. What is the IUPAC name of the product? a. Pentanoyl chlorideb. Pentanone chloridec. Pentanoic acid chlorided. Pentanyl chloride 3. The illustrated reaction mechanism is considered __________. a. Concertedb. Continuousc. Step-wised. Unfavorable 4. Which atom in the reaction mechanism is the nucleophile? a. Chloride anionb. Hydroxyl groupc. Methyl groupd. Carboxyl carbon 5. What type of reaction is illustrated in the reaction mechanism? a. Electrophilic substitution reactionb. Nucleophilic acyl substitution reactionc. Electrophilic acyl substitution reactiond. Nucleophilic addition reaction 6. What is the main functional group of the organic molecule? a. Alcohol functional groupb. Carboxyl functional groupc. Carbonyl functional groupd. Aldehyde functional group 7. Aside from the organic molecule, what product is…
What is the importance of proton transfer in the formation of ester? A.The carbonyl carbon is easily attacked by the nucleophile. B. The oxygen that has been attached to the two alkyl groups will become stable. C. The removal of a bulky substituent attached to the reactive site stabilizes the compound. D. none of the above
The Dess–Martin reaction reacts an alcohol with the Dess–Martin periodinane. The first step displaces one of the acetate groups on the periodinane with the alcohol. A base then deprotonates one of the alpha protons, forming a new carbonyl bond, iodinane and acetic acid. The oxidation stops at this stage to give the aldehyde. Both Swern and Dess–Martin conditions will also convert a secondary alcohol to a ketone. Now apply what has just been discussed. Draw the major organic product.
Thiols or thiol (-SH) group is a better base than hydroxide (-OH) group in elimination reactions.
What happens when water, alcohols or other protic solvents are used in Grignard reactions?
Label sets of equivalent hydrogen atoms on the alcohol product using alphabetical notation a, b, c etc.
As we have seen in this chapter, carbon-carbon double bonds are electron-rich regions that are attacked by electrophiles (e.g., HBr); they are not attacked by nucleophiles (e.g., diethylamine). However, when the carbon-carbon double bond has a carbonyl group adjacent to it, the double bond reacts readily with nucleophiles by nucleophilic addition (Section 19.8). Account for the fact that nucleophiles add to a carbon-carbon double bond adjacent to a carbonyl group and account for the regiochemistry of the reaction.
In Chapter 18, we will learn about the hydrolysis of acetals to aldehydes and ketones. Four of the seven steps in the mechanism for this process are shown in the conversion of acetal A to hemiacetal E. a.Add curved arrows for each step. b.Draw another resonance structure for C. c.Identify the nucleophile and electrophile in Step [3]. d.Which steps are Brønsted–Lowry acid–base reactions?

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