On the basis of this scheme, write down expressions for the net rates of change of theconcentrations [Cl2], [Cl], [CO], [COCl] and [COCl2].Assuming that the reactive intermediates Cl and COCl are in the steady-state regime showthat the rate of formation of COCl2 is given by the expression:At high concentrations of Cl2, how would the expression for the rate of formation of COCl2 simplify?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter18: Chemical Kinetics
Section: Chapter Questions
Problem 13P
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On the basis of this scheme, write down expressions for the net rates of change of the
concentrations [Cl2], [Cl], [CO], [COCl] and [COCl2].
Assuming that the reactive intermediates Cl and COCl are in the steady-state regime show
that the rate of formation of COCl2 is given by the expression:

At high concentrations of Cl2, how would the expression for the rate of formation of COCl2 simplify?

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