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- Show the relationship between E2 Reactions and Alkyne Synthesis ?1.- Why are carbon nanotubes and graphene currently considered as reinforcing additives for polymers? What effect do they have on the polymer? What is the mechanism by which they can enhance the Young’s modulus and tensile strength of a polymer? 2.- Kapton is the trade name of a polyimide a) How would you synthesize this polymer? b) During the first stage of the reaction, poly(amic acid) is formed. If you need to follow this stage of the polymerization, what spectroscopic techniques would you use and what groups should you focus on? c) How would you form Kapton films, which can be used as support for solar sails? d) What are the disadvantages of Kapton that have limited their use? Why does this polymer present this weakness?One of the heptanedione isomers below has a pka of approximately 9 rather than 20. Which isomer? Why? Draw its conjugate base and offer a full explanation of its acidity.
- After E2 elimination, will the following molecule contain deuterium? Why or why not?Choose the best reagents from the list provided below for carrying out the following conversion. Match the reagent with the step number. HCl (aq), Zn(Hg) KMnO4, H3O+ CH3Cl, AlCl3 HNO3, H2SO4 Cl2, FeCl3 fuming sulfuric acidWrite the order of increasing E1 reactivity. Highest reactivity placed on the left. *2-bromopropane *2-bromi-2-methylpropane *1-bromobutane *2-chloropropane *bromomethane
- What is the expected product of the reaction scheme below?CH₂ + Using the reagents below, list in order (by letter, no period) those necessary to prepare 2-butyne from acetylene. Note: Not all spaces provided may be needed. Type "na" in any space where you have no reagent. a. Br₂, heat, light b. Na, (-H₂) c. Nal(SN2) d. NH4NO3 e. 1) NaNH2, liq. NH3, 2) CH3Br f. (CH3)3COK, (CH3)3COH, heat g. NaOEt, EtOH, heat Step #1 Step #2 Step #3In the following three compounds(1,2,3) arrange their relative reactivity towards the reagent CH3Cl / AlCl3. Justify your order?
- 1. Which of the following is the strongest nucleophile? Refer to the diagram below with an MeOH, MeSH, etc. 2. Which of the following is true about the stereochemistry of SN1 reaction?a.retention of configuration at the electrophilic centerb.50:50 mixture of retention and inversion of configuration at the electrophilic centerc.inversion of configuration at the electrophilic centerd. slightly more inversion than retention at the electrophilic centerOrganometallic reagents and alkoxides are strong bases as well as being good nucleophiles. Given the pKa values below, which reagent is the stronger base, nBuLi (CH3CH2CH2CH2LI) or the tert-butoxide anion ((CH3)3CO‒)? Explain your choice clearly in terms of structure andbonding. (Comparing the pKa values is not an explanation.) (CH3)3COH pka= 16.54CH3CH2CH2CH3 pka= 50i need help filling out the following SN2 reactions with appopiate reactants, products, or reagents,