Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter20: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 3RQ
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When the copper (II) sulphate solution is reacted with a bidentate ligand such as ethylenediamine (en), the same thing would have happened. However, since one bidentate ligand has two donor atoms (Brown et al, 2017), each Cu2+ ion would only have 3 ligands at most, instead of 6 when reacted with monodentate ligands. The equation of the reaction is as follows:
[Cu(H2O)6]2+(aq) + 3en(aq) → [Cu(en)3](aq) + 6H2O(ℓ)
a. How do we know how many ligands can enter?
b. Explain briefly the discussion above.
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