Sample Solution from
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Chapter 1
Problem 37P
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Textbook Problem

Draw a Lewis structure for each of the following species:

  1. a. H2CO3
  2. b. CO32−
  3. c. CH2O
  4. d. CO2

Expert Solution

(a)

Interpretation Introduction

Interpretation:

Lewis structure of H2CO3 has to be drawn.

Concept Introduction:

A Lewis dot structure for an atom consists of a symbol for the element and one dot for each valence electron.

Steps in drawing a Lewis dot structure,

  • Total number of valence electron has to be known.
  • Atoms has to be distributed by the knowing the valency of each atom.
  • Form bonds and fill the octet with lone pair of electrons.
  • Formal charge if present has to be assigned.

Explanation of Solution

Given compound is H2CO3.

Number of valence electron of each atoms is identified and drawn as below,

images

Hydrogen can form only one bond, carbon can form four bonds and oxygen has six valence electrons.

Atoms have to be distributed by putting hydrogen on outside the molecule.

Here, there are two oxygen atoms, so avoiding the oxygen-oxygen single bonds.

The Lewis structure can be,

images or images

Each atom has to achieve an octet and the existing electron has to be shared.

Expert Solution

(b)

Interpretation Introduction

Interpretation:

Lewis structure of CO32 has to be drawn.

Concept Introduction:

A Lewis dot structure for an atom consists of a symbol for the element and one dot for each valence electron.

Steps in drawing a Lewis dot structure,

  • Total number of valence electron has to be known.
  • Atoms has to be distributed by the knowing the valency of each atom.
  • Form bonds and fill the octet with lone pair of electrons.
  • Formal charge if present has to be assigned.

Explanation of Solution

Given compound is CO32.

Number of valence electron of each atoms is identified and drawn as below,

images

Carbon can form four bonds and oxygen has six valence electrons.

Atoms have to be distributed by putting hydrogen on outside the molecule.

Here, there are two oxygen atoms, so avoiding the oxygen-oxygen single bonds.

images or images

Each atom has to achieve an octet and the existing electron has to be shared.

Expert Solution

(c)

Interpretation Introduction

Interpretation:

Lewis structure of H2CO has to be drawn.

Concept Introduction:

A Lewis dot structure for an atom consists of a symbol for the element and one dot for each valence electron.

Steps in drawing a Lewis dot structure,

  • Total number of valence electron has to be known.
  • Atoms has to be distributed by the knowing the valency of each atom.
  • Form bonds and fill the octet with lone pair of electrons.
  • Formal charge if present has to be assigned.

Explanation of Solution

Given compound is H2CO.

Number of valence electron of each atoms is identified and drawn as below,

images

Hydrogen can form only one bond, carbon can form four bonds and oxygen has six valence electrons.

Atoms have to be distributed by putting hydrogen on outside the molecule.

Here, there are two oxygen atoms, so avoiding the oxygen-oxygen single bonds.

The Lewis structure can be,

images or images

Each atom has to achieve an octet and the existing electron has to be shared.

Expert Solution

(d)

Interpretation Introduction

Interpretation:

Lewis structure of CO2 has to be drawn.

Concept Introduction:

A Lewis dot structure for an atom consists of a symbol for the element and one dot for each valence electron.

Steps in drawing a Lewis dot structure,

  • Total number of valence electron has to be known.
  • Atoms has to be distributed by the knowing the valency of each atom.
  • Form bonds and fill the octet with lone pair of electrons.
  • Formal charge if present has to be assigned.

Explanation of Solution

Given compound is CO2.

Number of valence electron of each atoms is identified and drawn as below,

images

Carbon can form four bonds and oxygen has six valence electrons.

Atoms have to be distributed by putting hydrogen on outside the molecule.

Here, there are two oxygen atoms, so avoiding the oxygen-oxygen single bonds.

images or images

Each atom has to achieve an octet and the existing electron has to be shared.

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