test 3 recitation

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University Of Georgia *

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1211L

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Chemistry

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Feb 20, 2024

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Recitation Worksheet Ten: Exam III Review Name: UGA ID: Instructions: § This recitation worksheet is a review for Exam III. § You do not need to submit it to Gradescope. § The answer key has been posted with this worksheet to eLC. § The recitation session during the exam week (October 30-November 2) is still mandatory . Your attendance will be recorded. § A periodic table and formula sheet are attached to the end of this worksheet. 1. An undergraduate student goes to chemistry lab to perform the bomb calorimetry experiment using benzoic acid (q comb = - 3225 kJ/mol; molar mass = 122.12 g/mol). They see a temperature change of approximately 4.10 ºC. If the heat capacity of the calorimeter is 12.1 kJ/ºC, what was the starting mass of benzoic acid used (in g)? g
2. A 6.16 g sample of benzene (C 6 H 6 ), an organic compound with a q comb = -41.74 kJ per gram of benzene, is combusted in a bomb calorimeter. What will the change in temperature of the bomb calorimeter be (in ºC) if the heat capacity of the calorimeter is 50.4 kJ/K? ºC 3. A bomb calorimetry experiment is performed with xylose, C 5 H 10 O 5 , as the combustible substance. The data obtained are: Mass of xylose burned: 1.183 g Heat capacity of calorimeter: 4.728 kJ/ºC Initial calorimeter temperature: 23.29 ºC Final calorimeter temperature: 27.19 ºC Based on this information, what is the heat of combustion of xylose in kJ/mol? kJ/mol
4. Given the information below, what is ∆H rxn for: C 3 H 4 (g) + 2 H 2 (g) → C 3 H 8 (g) H 2 (g) + ½ O 2 (g) → H 2 O (l) ∆H rxn = -285.8 kJ/mol C 3 H 4 (g) + 4 O 2 (g) → 3 CO 2 (g) + 2 H 2 O (l) ∆H rxn = -1937 kJ/mol C 3 H 8 (g) + 5 O 2 (g) → 3 CO 2 (g) + 4 H 2 O (l) ∆H rxn = -2219.1 kJ/mol kJ/mol 5. Given the information below, what is ∆H rxn for: CH 4 (g) + NH 3 (g) → HCN (g) + 3 H 2 (g)? N 2 (g) + 3 H 2 (g) → 2 NH 3 (g) ∆H rxn = -91.8 kJ/mol C (s) + 2 H 2 (g) → CH 4 (g) ∆H rxn = -74.9 kJ/mol H 2 (g) + 2 C (s) + N 2 (g) → 2 HCN (g) ∆H rxn = 270.3 kJ/mol kJ/mol
6. Given the following hypothetical reactions below... what is ∆H rxn for the reaction A (g) + 3 B (g) → D (g) + C (g)? kJ/mol
7. Of the following, ΔH° f is not zero for ________. 8. Consider the balanced reactions provided below. Which of the following are standard formation reactions? Select any that apply. 9. Calculate Δ r H° for the reaction below using standard enthalpies of formation provided in the table below. 4 NH 3 (g) + 5 O 2 (g) → 6 H 2 O (g) + 4 NO (g) Substance ΔH° f (kJ/mol) NH 3 (g) -45.9 NO (g) +91.3 H 2 O (g) -241.8 kJ A. O 2 (g) B. C (graphite) C. N 2 (g) D. F 2 (s) E. Cl 2 (g) A. C (s) + 2 H 2 (g) → CH 4 (g) B. 2 C (s) + 4 H 2 (g) → 2 CH 4 (g) C. 2 CO (g) + O 2 (g) → 2 CO 2 (s) D. CO (g) + ½ O 2 (l) → CO 2 (g) E. H 2 (g) + ½ O 2 (g) → H 2 O (g) F. H 2 (g) + ½ O 2 (g) → H 2 O (l) G. H 2 (g) + ½ O 2 (l) → H 2 O (l) H. 2 H 2 (g) + O 2 (g) → 2 H 2 O (l) I. CaO (s) + CO 2 (g) → CaCO 3 (s)
10. Calculate Δ r H° for the reaction below using standard enthalpies of formation provided in the table below. Fe 2 O 3 (s) + 3 CO (g) → 2 Fe (s) + 3 CO 2 (g) Substance ΔH° f (kJ/mol) Fe 2 O 3 (s) -824.2 CO (g) -110.5 CO 2 (g) -393.5 kJ 11. The value of ΔH° for the reaction below is -3351 kJ. The value of ΔH° f for Al 2 O 3 (s) is ________ kJ. 2 Al (s) + 3 O 2 (g) → 2 Al 2 O 3 (s) kJ
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