Lab 2
docx
keyboard_arrow_up
School
CUNY LaGuardia Community College *
*We aren’t endorsed by this school
Course
251
Subject
Chemistry
Date
Feb 20, 2024
Type
docx
Pages
4
Uploaded by ProfSkunk1926
Lab 2 SCC 251 Recrystallization
Organic Chemistry I SCC 251 276B
Abstract:
This lab is to learn how determine the perfect solvent for recrystallization out of three different compounds. In order to find the correct solvent for recrystallization, we put the solute in the solvent at
room temperature (RT) to see if dissolved or not. Then we dissolved the solutes boiling point (BP). The solutes used in the lab where Anthracene, Naphthalene, Resorcinol, and Benzoic Acid. In our experiment
we used Naphthalene, Benzoic Acid, and Unknown A. These solutes were used to find the appropriate solvents which are Ethanol, acetone, Water, Toluene. We used a small amount of solute which was 0.5mL with each solvent. After obtaining data of which solvent is the appropriate solvent for recrystallization, we put the data into tables to show what solutes are best for recrystallization. In order to find out what Unknown A is, we also must do melting point.
Data
Table 1 compounds dissolved in solutes Compound
Solubility in Methanol
Solubility in Acetone
Solubility in water
Melting point
Anthracene
Insoluble
Bp
Insoluble
251⁰C
Naphthalene
BP
RT, BP
Insoluble
80.26⁰C
Resorcinol
BP
BP
insoluble
110⁰C
Benzoic Acid
RT, BP
RT, BP
soluble
122.3⁰C
Discussion: In our data we had three different compounds and have determined a methanol and
H20 mixture is best solute for Naphthalene, was shown to be the best solvent for recrystallization. After Naphthalene we used Resorcinol, in this experiment it was shown that ethanol, acetone, and water were the best solvents for recrystallization. We also tested Benzoic acid; water was found to being the best solvent for recrystallization. It was difficult to find the solute for unknown A. water, acetone, methanol, and hexane did not work. We found out that toluene is the perfect solute for unknown A. After finding the solute for the unknown A we did a melting point in order to find out what compound it is. We started the melting point while Comparing it to all of the compounds melting points of the compounds we had. After comparing melting points, we had found that Unknown A is Anthracene due to it melting near at 251⁰C.
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
- Access to all documents
- Unlimited textbook solutions
- 24/7 expert homework help
Conclusion: I agree with the results I got in the experiment it did well on my expectations. I It was difficult finding the correct solute when the compound was unknown. Being able to know how to find the melting point is very important and being able to do all the steps of recrystallization is very important. Its very difficult to know when the compound is dry enough to do melting point. If there is still moisture it will affect the melting point causing incorrect results.
References: (1) (168) 1 O Chem Melting Point ALL with Graphics (CC) - YouTube
. https://www.youtube.com/watch?v=zMjl9MzpySU (accessed 2022-10-02).
(1) Irvine Valley College. 2 O Chem Recrystallization Procedure
; 2012.
(accessed 2022-10-02).
Related Documents
Related Questions
Only number 2. It has parts a , b, c
arrow_forward
Pls help ASAP ON ALL ASKED QUESTIONS PLS PLS
arrow_forward
A technician was analysing some waste water from an industrial plant. He collected 500 mL of the water and separated it into two 250 mL samples. He filtered one sample and evaporated the water from the other one. He weighed the dried solid residue from each sample. He found that the mass of solid from the filtered sample was 40 g and the mass from the evaporated sample was 55 g. What mass of soluble and insoluble material was in 1 L of the waste water?
arrow_forward
To prepare benzil you are heating a solution of benzoin with concentrated nitric acid. Following this, you will add water, cool the
mixture, and collect the solid. How will you treat/dispose of the left over liquid from this step?
Select an answer and submit. For keyboard navigation, use the up/down arrow keys to select an answer.
a
b
с
d
It must be neutralized with sodium bicarbonate and can then be washed down the drain.
It must be neutralized with sodium bicarbonate and then disposed of in the organic waste container.
It can be directly washed down the drain with lots of water.
It can be directly poured into the organic waste container.
arrow_forward
Gravimetric analysis is a quantitative method that involves measurement of volume of a solution of known concentration which is used to determine the concentration of the analyte.
True
False
A good example of complete analysis is the determination of %C, %H and %O in an unknown organic sample.
True
False
arrow_forward
1) In lab you are given 4 bottles, each containing about 5 grams of a white substance. Near the bottles are four labels indicating each bottle contains a high purity substance. Assume these labels belong to the bottles and that each bottle contains a single substance.
The four bottles contain glucose (C6H12O6), sodium chloride (NaCl), aluminum oxide (Al2O3), and zinc sulfate (ZnSO4).
Using your knowledge of solubility rules and electrolytic behavior, describe tests that you could conduct to determine which label belongs to which bottle. For these tests you may only use DI water, an aqueous solution of barium nitrate, and a conductivity tester to identify the substance in each of the bottles. Give the results you would expect for each test.
arrow_forward
Isotonic saline solution is 0.154 M NaCl(aq). What is the solubility of AgCl (Ksp = 1.8 × 10−10) in such a solution? Show your work.
a.
2.8 × 10−11 M
b.
1.2 × 10−9 M
c.
5.3 × 10−6 M
d.
0.077 M
e.
3.4 × 10−5 M
arrow_forward
Mg3(PO4)2 BaCO3
MgF₂
Most soluble
Least soluble
Fe(OH)3
Answer Bank
arrow_forward
Hd
10
5
0
5
mL of NaOH added
10
20
15
10
LO
5
0
arrow_forward
You dilute the river water 10 times for the analysis of SDS concentration. The instrument measures
an average molar concentration of SDS in the diluted river water to be 1.689 10-4 mol/L. The
molar mass of SDS is 288.4 g/mol.
What is the mass concentration of SDS in the original river water?
4.87 10-1 g/L
4.87 102 g/L
5.86 106 g/L
5.86 10-5 g/L
arrow_forward
Dilution means adding water to something so that the ratio of solute to solvent is less than in the original solution. Some people say, “Dilution is the solution to pollution.”
Do you think this statement true? Could you ever add enough water so that there would be no drink mix—that the water would be the same as in cup #6, pure water?
Do you think you could you ever add enough water to a pollutant to make it disappear completely? Why or why not?
arrow_forward
Here is a graph of the molarity of acetonitrile (CH, CN) in a reaction vessel during a certain chemical reaction. Use this graph to answer the questions in the
table below.
у
0.30-
0.25-
0.224
0.20
M
0.15–
0.10-
0.05
50
100
150
200
250
300
seconds
arrow_forward
wum Oxide and Sr(IO3)2•H20
Name:
POST-LAB QUESTIONS continued
Section
a. The solubility of barium iodate monohydrate in 25°C water is 0.028 g per 100. mL of
water. Calculate the solubility, or in other words, the proportion of how much product
would dissolve if you rinsed it with 125 mL of 25°C distilled water.
b. Suppose you have 4.832 g of product and then rinse it with 125 mL of 25°C water, use
the answer in 2a to calculate how much product would you expect to isolate.
C. The solubility of barium iodate monohydrate in 4°C water is 0.010 g per 100 mL of
water. Calculate the solubility, or in other words, how much product would dissolve if
you rinsed it with 20.0 mL of 4°C distilled water.
d. Suppose you have 4.832 g of product and then rinse it with 20.0 mL of 4°C water, use
the answer in 2c to calculate how much product would you expect to isolate.
e. Using your answers from (b) and (d), calculate the percent error or percent difference
as a result of accidentally using the 25°C…
arrow_forward
Can you help me understand how to get the dilution factors for each tube, please?
arrow_forward
Calculate the quantity of 0.250 M NaCl needed to prepare 250 ml of 0.010 M NaCl.
O a. 1 mL
Ob.100 ml
Oc. 0.1 ml
O d. 10 ml
arrow_forward
Calculate the concentration in ppm of Cd in a 2.00 mL sample which has been shown to contain 16.4 μg Cd. Assume the sample has a density of 1.00 g/mL.
a.
3.28 × 104
b.
8.20
c.
32.8
d.
8.20 × 10−3
e.
8.20 × 103
arrow_forward
Part Two: Types of Solutions (saturated, unsaturated, supersaturated)
On a solubility curve, the lines indicate the concentration of a
amount of solute that will dissolve at that specific temperature.
solution - the maximum
Values on the graph
could be dissolved at that temperature.
(below, above, on) a curve represent unsaturated solutions - more solute
Use the solubility curve on the first page to label the following solutions as saturated or unsaturated. If
unsaturated, write how much more solute can be dissolved in the solution.
Solution
If unsaturated: How
Saturated (S) or
Unsaturated (Un)?
much more solute can
dissolve in the solution?
a solution that contains
70g of NaNO3 at 30°C
a solution that contains
50g of NH.Cl at 50°C
a solution that contains
20g of KCIO3 at 50°C
a solution that contains
70g of KI at 0°C
arrow_forward
1. What is the concentration in ppm if 0.808 grams of CaCl2 is dissolved in 250 ml of water.
A. 11220 ppmB. 3220 ppmC. 2330 ppm
arrow_forward
POSTLABORATORY ASSIGNMENT
1. An oleic acid, C17H33COOH (282 g/mol), solution is added to water in a watchglass until a
monolayer forms. Assume that there are no spaces between molecules in the monolayer and
that each oleic acid molecule occupies an area of 0.25 nm². If the concentration of the oleic
acid solution is 0.00012 g/mL, what is the experimental value of Avogadro's number?
dropper pipet calibration
number of drops of oleic acid in the monolayer
diameter of monolayer
OMA 30+20 od os pulgad Im
od of
ingranit yd souls
mesto
bonstantial
=
|| || ||
00.1 arestusslom (0)
N =
=
=
Jorna ode
65 drops/mL
16 drops
14.5 cm
dirua orli unalools)
mano lo zemoristalls d
A(otho)
wall
arrow_forward
SEE MORE QUESTIONS
Recommended textbooks for you

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Related Questions
- Only number 2. It has parts a , b, carrow_forwardPls help ASAP ON ALL ASKED QUESTIONS PLS PLSarrow_forwardA technician was analysing some waste water from an industrial plant. He collected 500 mL of the water and separated it into two 250 mL samples. He filtered one sample and evaporated the water from the other one. He weighed the dried solid residue from each sample. He found that the mass of solid from the filtered sample was 40 g and the mass from the evaporated sample was 55 g. What mass of soluble and insoluble material was in 1 L of the waste water?arrow_forward
- To prepare benzil you are heating a solution of benzoin with concentrated nitric acid. Following this, you will add water, cool the mixture, and collect the solid. How will you treat/dispose of the left over liquid from this step? Select an answer and submit. For keyboard navigation, use the up/down arrow keys to select an answer. a b с d It must be neutralized with sodium bicarbonate and can then be washed down the drain. It must be neutralized with sodium bicarbonate and then disposed of in the organic waste container. It can be directly washed down the drain with lots of water. It can be directly poured into the organic waste container.arrow_forwardGravimetric analysis is a quantitative method that involves measurement of volume of a solution of known concentration which is used to determine the concentration of the analyte. True False A good example of complete analysis is the determination of %C, %H and %O in an unknown organic sample. True Falsearrow_forward1) In lab you are given 4 bottles, each containing about 5 grams of a white substance. Near the bottles are four labels indicating each bottle contains a high purity substance. Assume these labels belong to the bottles and that each bottle contains a single substance. The four bottles contain glucose (C6H12O6), sodium chloride (NaCl), aluminum oxide (Al2O3), and zinc sulfate (ZnSO4). Using your knowledge of solubility rules and electrolytic behavior, describe tests that you could conduct to determine which label belongs to which bottle. For these tests you may only use DI water, an aqueous solution of barium nitrate, and a conductivity tester to identify the substance in each of the bottles. Give the results you would expect for each test.arrow_forward
- Isotonic saline solution is 0.154 M NaCl(aq). What is the solubility of AgCl (Ksp = 1.8 × 10−10) in such a solution? Show your work. a. 2.8 × 10−11 M b. 1.2 × 10−9 M c. 5.3 × 10−6 M d. 0.077 M e. 3.4 × 10−5 Marrow_forwardMg3(PO4)2 BaCO3 MgF₂ Most soluble Least soluble Fe(OH)3 Answer Bankarrow_forwardHd 10 5 0 5 mL of NaOH added 10 20 15 10 LO 5 0arrow_forward
- You dilute the river water 10 times for the analysis of SDS concentration. The instrument measures an average molar concentration of SDS in the diluted river water to be 1.689 10-4 mol/L. The molar mass of SDS is 288.4 g/mol. What is the mass concentration of SDS in the original river water? 4.87 10-1 g/L 4.87 102 g/L 5.86 106 g/L 5.86 10-5 g/Larrow_forwardDilution means adding water to something so that the ratio of solute to solvent is less than in the original solution. Some people say, “Dilution is the solution to pollution.” Do you think this statement true? Could you ever add enough water so that there would be no drink mix—that the water would be the same as in cup #6, pure water? Do you think you could you ever add enough water to a pollutant to make it disappear completely? Why or why not?arrow_forwardHere is a graph of the molarity of acetonitrile (CH, CN) in a reaction vessel during a certain chemical reaction. Use this graph to answer the questions in the table below. у 0.30- 0.25- 0.224 0.20 M 0.15– 0.10- 0.05 50 100 150 200 250 300 secondsarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning