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Advantages And Disadvantages Of Pervaporation

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Observed first in 1919 by P.A. Kober, pervaporation, as the name delineates, incorporates permeation of a component into the involved membrane matrix and the successive evaporation of the permeated component into the vapour phase inside the membrane matrix. The vapour-liquid interface is extant inside the membrane. The component from the liquid feed that permeates into the membrane vaporizes into its corresponding vapour state in situ and gets selectively permeated to the other side which depends on the difference between the transport rates of the components in the liquid feed. Generally, the feed or the upstream side is at atmospheric pressure, while the permeate or the downstream side is kept under vacuum so as to allow the selective evaporation of the target component after permeation through the membrane (der Bruggen et al., 2015). The driving force is the differences in partial pressures of the components on either side of the membrane. A thing of note: the volatility difference between the feed components does not play any role whatsoever in determining the selectivity of the components (Huang et al., 2008). The mechanism involved in pervaporation is the solution-diffusion model.
Pervaporation membranes can be classified depending on the material used for their construction i.e organic, inorganic and …show more content…

The PDMS, PTMSP, zeolite and composite membranes have been reported to have separation factors of 4.4–10.8, 9–26, 7–59, 12–106, respectively. However, in some cases, the separation factor gets way higher than expected, such as a separation factor of 218 during the separation of ethanol (98.2% permeate) over water-ethanol solution (20% by weight ethanol), using a silicate zeolite membrane (Nomura et al., 2002). In general, separation factors are ranked in the following order: PDMS < PTMSP < composite membranes < zeolite

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