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Approach to Reduce Cathodic Voltage Losses

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Another approach to reduce the cathodic voltage losses is to replace metal based electrocatalyst with semi-conductor aided by a renewable energy source, such as solar energy. This resulted in the development of photo-electrocatalysts for MFC applications, which significantly improved the cathodic ORR 30,32. In this innovative application, there are robust synergies between the anode respiration and photo-electrocatalysis of ORR in the cathode (Figure 7). In this new design which known as solar microbial photo-electrochemical cell (MPC), the electron–hole pairs are liberated upon illumination of semi-conductor electrocatalyst. After that, the generated charges (holes and electrons pairs) are moved into the catalytically active site for electrocatalytic reactions, meanwhile electrons are delivered from the anode to combine with holes or directly participate in cathodic reactions. Figure 7. (a) Schematic diagram of a solar MPC, and (b) The corresponding energy diagram (source: Qian et al. 2010). Thus, to enable such synergies, the photoelectrocatalyst should possess the following three properties. (1) The material should be conductive and active for the electrocatalytic reactions. (2) It should be able to absorb light (ideally visible light) and transport the photo-excited electrons. These two properties don’t have to be provided by the same material. That means, a photoelectrocatalyst may consist either of an absorber that is catalytically active by itself or of a structure

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