Demarcay Radioactive Barium Chloride

In the early 1900’s, the discovery of a luminescent material, radium, arrived on the scene to the delight of a fascinated and eager public. At first, it seemed to be a miracle remedy, not just harmless but even beneficial. However, when a multitude of watch dial painters were exposed to this substance on an extremely consistent basis, the negative effects began bubbling to the surface. These “Radium Girls” were unknowingly consuming a potentially lethal substance and would be the first victims of radium poisoning and radioactivity. Not many people knew about the dangers of radioactive substances or radium poisoning and many others had made judgements that were clouded by the perfection of the glowing sensation. In spite of this, the horrific afflictions that the Radium Girls endured helped shift the public perspective of radium from “wonder drug” to “pitiless poison” and started the country on a path to regulating the handling of radioactive

In 1898, Marie and Pierre Curie announced they had discovered a new element that “behaved like pure barium” to the world. They named it radium for its radioactive properties. The Curies would have to prove their discovery with copious amounts of radium, and to do so needed to extract it on its own. They used the ore of pitchblende, which was high in supply in the Joachimsthal mine in Bohemia, to experiment with extracting the radium (Fröman, 2014). Marie used the process of boiling the pitchblende in acid used for cleaning and bleaching, which then left her with radium mixed with other metals. She then boiled what was left with a different solution and washed it, which cleared it of some of the metals (McClafferty, 2006). Marie boiled the remaining compound in another solution, washed it with water, and treated it with corrosive agents. These extensive processes allowed Marie to separate the metals from the radium sulfate and barium sulfate. To turn the sulfates into radium salt, she boiled them again.

When Henri Becquerel discovered radioactivity in 1896, it inspired Marie and Pierre to investigate it further. They researched a lot of substances for any signs of radioactivity, and discovered something that was more radioactive than uranium. They discovered radium, an element that damaged tissue, so they used that to fight against cancer. “They found that the mineral pitchblende was more radioactive than uranium and concluded that it must contain other radioactive substances. From it they managed to extract two previously unknown elements, polonium and radium, both more radioactive than uranium” (Nobel Media). These discoveries led to radium being used to treat cancer and other diseases, and them getting their first Nobel Prize in Physics in 1903. After Pierre passed away, she continued with her own studies. Marie successfully isolated radium and proved its existence. She also studied the properties and compounds of these radioactive elements. “She also documented the properties of the radioactive elements and their compounds. Radioactive compounds became important as sources of radiation in both scientific experiments and in the field of medicine, where they are used to treat tumors” (Nobel Media). This discovery led to the further development of X-rays and her receiving her second Nobel Prize in Chemistry in 1911. Marie Curie was the first woman ever to win two Nobel Prizes in two fields and in multiple sciences, two incredible

The pioneering work of Becquerel in 1896 (the discovery of uranium), and the Curies (who subsequently discovered radium and polonium and the energy and heat given off by these new elements which they called radioactivity) led to the remarkable work of Ernest Rutherford. He was a physicist, whose experiments showed that some heavier elements spontaneously changed or decayed into lighter elements (unstable 'parent' elements giving off protons and neutrons to form a 'daughter' element) through the process of radioactivity. He discovered that radioactive materials decay at a very predictable rate, and that lead was the final decay product of uranium. Using Rutherford's ideas, Bertram Boltwood pioneered a method of radiometric dating in 1907. He hypothesized that since he knew how long it takes uranium to break down, he could measure the proportions of lead in uranium ores, and use his calculations to date how long those ores had existed,

who said “All this colonial business is a sham, but we need it for elections”

Radium appears as a shiny, silvery metal of high radioactivity. Radium can be “used to treat prostate cancer that has spread to the bones,” and in the past, it was “used in luminous paints, for example in clock and watch dials” (Royal Society of Chemistry, 2017). Radium is present in the environment, and people that live in areas where coal or other fuels are burning and released into the air are more exposed to higher levels of radium. Radium can enter the body by breathing or swallowing and can remain in the body for months, only exiting in small amounts by urine and feces (“Public Health Statement for Radium,” 1990). High levels of radium exposure over a long period of time are extremely dangerous to the health of an individual. The harmful effects of radium could cause “anemia, cataracts, fractured teeth, cancer (especially bone cancer), and death” (“Public Health Statement for Radium,” 1990). The greater amount of radium exposure an individual receives, the greater their chance is to developing one of these diseases (“Public Health Statement for Radium,”

It is now known that radium, shown in figure 4, is a potent carcinogen (a substance the cause’s cancer (Wilbraham, Staley, Marta, & Waterman, 2005)). It emits a form of ionizing radiation which “includes electromagnetic radiation (e.g., gamma rays and X-rays) as well as particles (e.g., alpha particles, beta particles, high-speed neutrons, high-speed electrons, high-speed protons, etc.)” (National Library of Medicine, n.d.). Acute studies have been done on the effects of radium exposure on the human body by organizations like the Geneva World Health Organization, the International Agency for Research on Cancer, and Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man. As a result of their findings, The National Library of Medicine states that sufficient evidence has been provided showing that prolonged exposure to Raduim-224, Radium-226,

In the course of the last four months it has been made probable--through the work of Joliot in France as well as Fermi and Szilard in America--that it may become possible to set up a nuclear chain reaction in a large mass of Uranium, by which vast amounts of power and large quantities of new radium-like elements would be generated. Now it appears almost certain that this could be achieved in the immediate future. (Einstein)

The story of radium girls has to begin with the discovery of radium in 1898 by

Scandium was founded by Lars F. Nilson in 1879, In Uppsala, Sweden. Nilson was studying the other rare earth elements trying to isolate ytterbium another different chemical from the two minerals euxenite and gadolinite. Part of the experiment was to prepare the erbia (erbium oxide) from the other minerals which then reacts with the other chemicals to form another chemical named erbium nitrate, Nilson then added heat to the Nitrate and then found his sample had small quantities of an unknown element with a small atomic weight. A spectral analysis showed that this “element” had thirty unique spectral lines, proving that it was confirmed a new element.

Curie thus began studying uranium radiation and made it her doctoral thesis. With the aid of an electrometer built by Pierre, Marie measured the strength of the radiation emitted form uranium compounds and found it proportional to the uranium content, constant over a long period of time and influenced by external conditions. She detected a similar immutable radiation in the compounds of thorium. While checking these results, she made the discovery that uranium pitchblende and the mineral chalcolite emitted four times as much radiation as their uranium content. She realized that unknown elements, even more radioactive then uranium must be present.

Radioactivity is defined as “the spontaneous emission of particles”. (Nuclear Energy). Radioactivity is caused by an unbalanced nucleus in the cell. This happens because there is either an uneven number of protons and/or neutrons. When this happens, the element is considered to have multiple isotopes. An isotope is an atom with the same number of protons but a different number of neutrons. Thus, they have different atomic weights. This is important to know because there is a such thing as a radioactive isotope. These elements just have additional energy, and they release radiation in different forms. “There are over 800 radioactive isotopes, some of which are natural and some synthetic.” (Helmenstine). Radioactive elements can be both artificial and natural. However, in medicine, most of them are more than likely synthetic, since they are the most popular types.

     It was not easy for Marie and Pierre to convince the science community of their new findings. Marie succeeded in separating the radium from the barium, but it wasn't easy. She had to treat very large amounts of pitchblende, but she had plenty of pitchblende to use. (The Curie's

This is what led Curie to take Becquerel’s work a few steps further and conduct her own experiments on uranium rays. She discovered that the rays were constant no matter what form or condition of the uranium. She theorized the rays came from the atomic structure. This idea was revolutionary and created its own field in science, known as the atomic physics, this is when Marie coined the word “radioactivity” to describe the phenomena. Even when they had their first daughter Irene in 1897 there work did not slow. Pierre then stopped his own studies to help Marie with her new discovery of radioactivity. In 1898 they discovered a new radioactive element. They named it polonium after Marie’s native country, Poland. They detected the presence of another radioactive element and called this radium. In 1902 they had extracted pure radium to prove its existence as a unique chemical element.

With her experiments, she became the first woman in France to get a doctorate. Curie decided to continue Henri Becquerel’s experiments with X-rays. She came up with the groundbreaking idea that the rays were actually an atomic property. The paper she wrote reporting her discoveries had to be presented through her professor because women weren’t allowed to address the Academy of Sciences. With this, she continued her work to find new elements. First, she found polonium, which is named for her home country, and then she discovered radium. Pierre and Marie’s greatest work was done in a run-down shed. They worked from 1898 to 1902. The Curies could have made a fortune if they patented their process of extracting and refining radium, but they decided share their knowledge with the world.