Determination of the Enthalpy of Reaction of a Monobasic Acid with Sodium Hydroxide

In this experiment, the results of the tested materials gave off heat and the change in the temperature was positive because when one substance was added to another the temperature increased. A calorimetric constant is required because the calorimeter that was made is different for every lab group.

    In this lab, a calorimeter was used to find the enthalpy of reaction for two reactions, the first was between magnesium and 1 molar hydrochloric acid, and the second was between magnesium oxide and 1 molar hydrochloric acid. After the enthalpy for both of these were found, Hess’ law was used to find the molar enthalpy of combustion of magnesium, using the enthalpies for the two previous reactions and the enthalpy of formation for water. The enthalpy of reaction for the magnesium + hydrochloric acid reaction was found to be -812.76 kJ. The enthalpy of reaction for the magnesium oxide + hydrochloric acid reaction was found to be -111.06 kJ. These two enthalpies and the enthalpy of formation for water were manipulated and added together using Hess’s law to get the molar enthalpy of combustion of magnesium. It was found that the molar enthalpy of combustion of magnesium was -987.5 kJ/mol. The accepted enthalpy was -601.6 kJ/mol, which means that there is a percent difference of 64%. This percent difference is very high which indicates that this type of experiment is very inefficient for finding the molar enthalpy of combustion of magnesium. Most likely, a there are many errors in this simple calorimeter experiment that make it inefficient for finding the molar enthalpy of combustion of magnesium.

The purpose of this semester long experiment was to determine an unknown organic acid. An organic acid is an organic compound with acidic properties. A base reacts with acids to form salts. Titrations are used to determine the concentration of unknown substances. The purpose of the KHP experiment was to determine the molarity of NaOH. HCl titrations are mainly to check technique and used to verify the molarity of NaOH solution. The hypothesis is that this acid is C4H3OCOOH.

The purpose of this experiment was to determine the pKa, Ka, and molar mass of an unknown acid (#14). The pKa was found to be 3.88, the Ka was found to be 1.318 x 10 -4, and the molar mass was found to be 171.9 g/mol.

Experiment 2 focused on finding the enthalpy of solution of magnesium chloride. Testing the enthalpy of solution started with measuring out 10 mL of deionized water in a graduated cylinder for three separate trials, each trial having a different mass of magnesium chloride. The water was then poured into a well of a Styrofoam calorimeter then the initial temperature of water was taken using a temperature probe and the LoggerPro programming. A measured amount of magnesium chloride was placed in the same well as the water in the calorimeter,

Procedure: Filled each test tube with substances provided and subjected them to various conditions. These conditions included, heat, cold water, hot water, acid and basic additions and tested on litmus paper. The reactions were observed and documented at each step.

Chemistry 102 is the study of kinetics – equilibrium constant. When it comes to the study of acid-base, equilibrium constant plays an important role that tells how much of the H+ ion will be released into the solution. In this lab, the method of titrimetry was performed to determine the equivalent mass and dissociation constant of an unknown weak monoprotic acid. For a monoprotic acid, it is known that pH = pKa + log (Base/Acid). When a solution has the same amount of conjugate base and bronsted lowry acid, log (Base/Acid) = 0 and pH = pKa. By recording the pH value throughout the titration process and determining the pH at half- equivalence point, the value of Ka can be easily calculated. In this experiment, the standardized NaOH solution has a concentration of 0.09834 M. The satisfactory sample size of known B was 0.2117 g. The average equivalent mass of the unknown sample was found to be 85.01 g, pKa was found to be 4.69, which was also its pH at half-equivalence point and Ka was found to be 2.0439×〖10〗^(-5). The error was 1.255% for equivalent mass and 0.11% for Ka. In other word, the experiment was very precise and accurate; the identity of the unknown sample was determined to be trans-crotonic by the method of titrimetry.

To learn about standard enthalpies of formation and using this to predict if the reaction is exothermic or

The independent variable for this experiment will be the the temperature of the acids used for the reaction between the alka seltzer tablet. Four trials will be tested the temperature will be 25C, 45C, 65C, and 85C. Starting off the first trial will be 25 C (room temperature) and will increase each trial by 20C. Both the acids will have a molarity of 1 and the amount used for each of the trials is 20ml.

If 10.0g of solid baking soda is poured into 30 mL of citric acid, then a reaction will occur and an increase in temperature will be observed. Whereas, if a piece of magnesium metal is added to 30 mL of Hydrochloric Acid, then a reaction will occur and an increase in temperature will be observable. For Part 3 of the experiment, if 50 mL of tap water is placed in a can 2.5 cm inches above a burning marshmallow, then through the process of calorimetry the energy content of the marshmallow should be 5.0kJ/g (the value provided by the United States Department of Agriculture).

The purpose of this lab was to experiment with triprotic acid to create different salts through neutralization. Specifically, using varying volumes of sodium hydroxide with a constant 1 mL of 6M Phosphoric acid. In doing so one can examine the reactions and use stoichiometry to identify the products formed from the relationship between the reagents.

The literature value for the enthalpy change of the last reaction which was provided by our teacher is -97 kJ mol-1. Agreeing this value, our result can be considered accurate.

This experiment was performed to determine the heat of neutralization between Hydrogen chloride (HCl) and Sodium hydroxide (NaOH). A temperature probe was used to measure the temperature of the reaction when the base (NaOH) was poured into the acid (HCl). The data was collected on logged on LoggerPro.

Purpose: To measure the heats of reaction for three related exothermic reactions and to verify Hess’s Law of Heat Summation.

Introduction: Every chemical change is accompanied by a change in energy usually in the form of heat. If heat is evolved, the reaction is exothermic, and if heat is absorbed, the reaction is endothermic. The energy change of a reaction that occurs at constant pressure is called the heat of reaction or the enthalpy of reaction (ΔHr). This quantity of heat is measured experimentally by allowing the reaction to occur in a calorimeter. In this experiment you will determine the heat of neutralization when an acid and a base react to form 1 mole of water. In a perfect calorimeter, heat is exchanged only between the reaction and the calorimeters water. Technically, some heat may may be absorbed the calorimeter. All calorimeters exchange some heat with its environment. This amount of heat is called the calorimeters heat capacity (the amount of of heat required to raise its temperature 1∘Celsius). We are going to “pretend” that our calorimeter is the perfect calorimeter.