preview

Determination of the Solubility Product Constant of Calcium Hydroxide

Good Essays

DETERMINATION OF THE SOLUBILITY PRODUCT CONSTANT OF CALCIUM HYDROXIDE

ABSTRACT This experiment aimed to determine the solubility product constant (Ksp) of Ca(OH)2 as well as to evaluate the effects of common and non-common ions on its solubility. Ca(OH)2 solids were dissolved in eight various media: distilled water, 1.0 M KCl, 0.5 M KCl, 0.1 M KCl, 0.05 M KCl, 0.005 M KCl, 0.001 M KCl, and 0.1 M Ca(NO3)2. The concentration of dissociated OH- concentrations was determined by means of titrimetric analysis with 0.1 M HCl. The [OH-] values were then used to calculate the solubility and Ksp of Ca(NO3)2 in each medium. Furthermore, a plot of the ionic strength and the solubility values for the KCl media was made. In conclusion, although there …show more content…

The calculated values from here were used to graph a plot of s against μ. This was used for the analysis of the effect of diverse-ions in the solubility of ionic solids.

Figure 1 shows a flowchart of the general procedure of the experiment. Precipitation of Calcium Hydroxide The Ca(OH)2 precipitate was obtained by gradually adding 10 mL of 1.0 M Ca(NO3)2 to 20 mL 1.0 M NaOH solution until saturated. All Ca2+ ions were assumed to have completely reacted with the OH- ions which was shown in the addition of excess NaOH. Upon mixing Ca(NO3)2 with NaOH dropwise, the solution was stirred thoroughly to make sure that all Ca2+ ions will react with the OH2

ions in order for the desired precipitate to be formed. The saturated solution was then filtered and washed with distilled water, ethanol, and acetone, keeping the solid on the filter paper. This part was done in that particular order because of practical reasons. Some of the precipitate was stuck in the sides of the beaker so it must be washed with distilled water and naturally, the wash water must pass through the filter paper as well. Since ethanol and acetone evaporates quickly, they were also used in washing the precipitate so that it will dry off faster. Ethanol

Get Access