DETERMINATION OF THE SOLUBILITY PRODUCT CONSTANT OF CALCIUM HYDROXIDE
ABSTRACT This experiment aimed to determine the solubility product constant (Ksp) of Ca(OH)2 as well as to evaluate the effects of common and non-common ions on its solubility. Ca(OH)2 solids were dissolved in eight various media: distilled water, 1.0 M KCl, 0.5 M KCl, 0.1 M KCl, 0.05 M KCl, 0.005 M KCl, 0.001 M KCl, and 0.1 M Ca(NO3)2. The concentration of dissociated OH- concentrations was determined by means of titrimetric analysis with 0.1 M HCl. The [OH-] values were then used to calculate the solubility and Ksp of Ca(NO3)2 in each medium. Furthermore, a plot of the ionic strength and the solubility values for the KCl media was made. In conclusion, although there
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The calculated values from here were used to graph a plot of s against μ. This was used for the analysis of the effect of diverse-ions in the solubility of ionic solids.
Figure 1 shows a flowchart of the general procedure of the experiment. Precipitation of Calcium Hydroxide The Ca(OH)2 precipitate was obtained by gradually adding 10 mL of 1.0 M Ca(NO3)2 to 20 mL 1.0 M NaOH solution until saturated. All Ca2+ ions were assumed to have completely reacted with the OH- ions which was shown in the addition of excess NaOH. Upon mixing Ca(NO3)2 with NaOH dropwise, the solution was stirred thoroughly to make sure that all Ca2+ ions will react with the OH2
ions in order for the desired precipitate to be formed. The saturated solution was then filtered and washed with distilled water, ethanol, and acetone, keeping the solid on the filter paper. This part was done in that particular order because of practical reasons. Some of the precipitate was stuck in the sides of the beaker so it must be washed with distilled water and naturally, the wash water must pass through the filter paper as well. Since ethanol and acetone evaporates quickly, they were also used in washing the precipitate so that it will dry off faster. Ethanol
In this experiment, it is very important to ensure that the deionized water is just basic and not acidic in order to obtain accurate results. Calcium oxalate does not precipitate in an acidic solution because of the formation of H2C2O4-, an ion that does not precipitate with Ca2+ . Allowing the precipitate to settle is also very
Purpose: To determine the percent magnesium by mass in magnesium oxide and to observe if the percentage composition is constant by comparing class results.
The two most obvious formation of the precipitate were the combinations with the MgSO4. The MgSO4 and NH3 solution became very opaque and the MgSO4 and Na2CO3 turned from liquid to a full solid white substance. The Na2CO3 and CH3COOH did not have as strong of a reaction, however, the precipitates were able to be visualized with in the clear
The pre-test helped us decide the exact details of our experiment. We started off with testing 25cm³ of 3-molar hydrochloric acid to 2g of calcium carbonate medium size chips (we decided a medium size chips before we started our pre-test as we had a choice of 3, small, medium, large). We saw that this reacted too quickly as we used 10 second intervals and we couldn't get 6 results this is because our burette could only hold 100cm³ of water, which would make our results reliable. We then decreased the amount of Calcium Carbonate to 1g and kept the same 25cm³ of 3 molar hydrochloric acid and 10 second intervals. We could get the right amount of results of this, so we then tested the other extreme - the lowest molarity.
6. The solubility of the solids were tested using a micro tray, by placing them in water and oil to observe their polarity,
(Hint the concentration of calcium ions in well 12 is 4.9 x 10-5 M.) Place 5 drops of 0.10 M NaOH in each of the wells 1 through 12. When the NaOH is added to each well, the initial concentrations of the reactants are halved, as each solution dilutes the other. Use an empty pipet to mix each of these combined solutions by drawing each solution up into the pipet and squirting it back into the well. (Hint the concentration of Ca2 ions in well 12 is 2.4 x 10-5 M.) Allow three or four minutes for the precipitates to form, then observe the pattern of precipitation. At one point the concentration of both ions becomes too low to have any precipitate form. We will assume that the first well with no precipitate represents a saturated solution. Part B NaOH varies, Ca(NO3)2 held constant To check your results, repeat the procedure but use a serial dilution of the NaOH. In a different row, put 5 drops of 0.10-M NaOH in well 1. Put 5 drops of distilled water in wells 2 through 12. Add 5 drops of the 0.10-M NaOH solution to well 2. Use an empty pipet to mix the solution by pulling the solution into the pipet and then squirting it back several times. The solution in this well, 2, is now 0.050 M in OH- ion. Continue this serial dilution to well 12, and then remove 5 drops from well 12. Add 5 drops of 0.10 M Ca(NO3)2 to each of the wells, and mix each with an empty pipet or stirrer. Again, determine the well where no more precipitate appears. Cleanup
Solutions of 6M H2SO4, 6M NH3, 6M HCl, 6M NaOH, and 1.0 M of NaCl, 1M Fe(NO3)3, 1M NiSO4, 1M AgNO3, 1M KSCN, 1M Ba(NO3)2, and 1M Cu(NO3)2 were given in separate test tubes. The color of possible precipitates, ions, acid-base behaviour, odor and solubility rules were conducted and were reported in Table 1. The key information about a mixture of two solutions was
Ionic compounds are soluble in water to a certain point depending on the compound. The level of solubility changes among different compounds. Some ionic compounds can completely dissolve in water and appear to be a homogeneous mixture. Although, some ionic compounds dissolve very little, and could be considered insoluble, since it does not dissolve fully. Depending on the compound, the level of solubility can be high or low. However, ionic compounds could dissolve to a certain degree. If the solution appears to be a heterogeneous mixture, many may assume through visual representation that it may be insoluble. As stated previously, the smallest amount of solubility should be considered. To confirm whether or not the substance is soluble, observe the efficiency when conducting electricity. Due to practical reasons, the slightest solubility could be considered insoluble by people.
The purpose of this experiment was to identity, analyze and synthesize an unknown white compound. The identity of the unknown compound was determined by a flame and ion test to identify the cation and anion present in the compound. To confirm the identity, an ammonium test and conductivity test was conducted. After, the unknown compound, which was identified as Calcium(II)Nitrate, was synthesized in an acid-base reaction between Nitric Acid and Calcium Carbonate. The increments used were done so in order to obtain a theoretical yield of 1.0 gram of Ca(NO3)2.
2) Explain the trend in the solubility of the three alcohols in water. (In your discussions, bring out the theoretical concepts on which
For the cation analysis, 0.566 g of an unknown compound was dissolved completely in 5mL of distilled water in a centrifuge tube, thus confirming this solution as a stock solution. A flame test was performed on the stock solution to give a general idea of what test was to e preformed on the stock solution deriving the information from our logic trees in part 1. The logic tree from part 1 and the flame test confirmed that we needed to conduct an ammonia test on the stock solution. To being the ammonia test, 15 M NH4OH was added drop wise (about 20 drops) to the stock and the color of the solution and the color of the solution was recorded. 10 more drops of 15 M NH4OH
In this experiment, the experimenter will determine the chemical formula for the copper chloride hydrates using the law of definite proportions. The hydrated compound has a general formula of CuxCly•zH2O, with the variables x, y, and z. The variables represent the whole number ratio of moles that will be the “true” chemical formula of the hydrate. The chemical formula shows the number of atoms of each element in a compound.
The purpose of this experiment was to determine which double displacement reactions will form a precipitate or a gas.
In this experiment, a saturated calcium sulfate was already made and ready to use. 25.00 mL of this solution was then mixed with 10 mL of an ammonia buffer and 1 drop of
The cations in both the known and unknown samples were identified by using qualitative analysis, of which were determined to be acidic, basic, or neutral by using litmus paper. Acid-base reactions, oxidation-reduction reactions, and the formation of complex ions are often used in a systematic way for either separating ions or for determining the presence of specific ions. When white precipitate formed after adding hydroxide, aluminum ion was determined to be present in the solution. However, nickel was determined to test positive when the solution changed to a hot pink color after adding a few drops of dimethylglyoxime reagent and iron was present when the solution was a reddish brown color when sodium hydroxide was added to the mixture at the very beginning of the experiment. Qualitative analysis determines that ions will undergo specific chemical reactions with certain reagents to yield observable products to detect the presence of specific ions in an aqueous solution where precipitation reactions play a major role. The qualitative analysis of ions in a mixture must add reagents that exploit the more general properties of ions to separate major groups of ions, separate major groups into subgroups with reactions that will distinguish less general properties, and add reagents that will specifically confirm the presence of individual