Determining The Equivalent Mass And Dissociation Constant Of An Unknown Weak Acid
Ka Chun Wong, and James Ross, Ph.D.
East Los Angeles, Chemistry Department,
1301 Avenida Cesar Chavez, Monterey Park, CA 91754
Abstract
Chemistry 102 is the study of kinetics – equilibrium constant. When it comes to the study of acid-base, equilibrium constant plays an important role that tells how much of the H+ ion will be released into the solution. In this lab, the method of titrimetry was performed to determine the equivalent mass and dissociation constant of an unknown weak monoprotic acid. For a monoprotic acid, it is known that pH = pKa + log (Base/Acid). When a solution has the same amount of conjugate base and bronsted lowry acid, log (Base/Acid) = 0 and pH = pKa. By recording the pH value throughout the titration process and determining the pH at half- equivalence point, the value of Ka can be easily calculated. In this experiment, the standardized NaOH solution has a concentration of 0.09834 M. The satisfactory sample size of known B was 0.2117 g. The average equivalent mass of the unknown sample was found to be 85.01 g, pKa was found to be 4.69, which was also its pH at half-equivalence point and Ka was found to be 2.0439×〖10〗^(-5). The error was 1.255% for equivalent mass and 0.11% for Ka. In other word, the experiment was very precise and accurate; the identity of the unknown sample was determined to be trans-crotonic by the method of titrimetry. Introduction…
-
This is a chemistry lab report on an Acid-Base Titration experiment.
2714 Words | 11 PagesFull Lab Report Experiment #2: Acid-Base Titration Lab Description: Acid-Base Titration Introduction In this lab exercise we will evaluate the effectiveness of several indicators for the determination of the point of completion of a specific acid-base neutralization reaction. We will also determine the unknown concentration of the strong base NaOH by its reaction with a known amount of the weak acid, potassium acid phtalate (HKC8H4O4, abbreviated KHP). This will be accomplished using the titration…
-
Synthesis of Salicylic Acid and Potentiometric Determination of Its Purity and Dissociation Constant
4209 Words | 17 PagesSynthesis of Salicylic Acid and Potentiometric Determination of its Purity and Dissociation Constant ------------------------------------------------- Abstract The purpose of the study is to synthesize salicylic acid from the ester, methyl salicylate, and determine the acid’s dissociation constant and purity. The ester was converted to salicylic acid by base hydrolysis. The products were refluxed and recrystallized, to ensure maximum purity, and filtered, dried, and weighed. The melting point…
-
Studying the pH of Strong Acid, Weak Acid, Salt, and Buffer Solutions
1676 Words | 7 PagesStudying the pH of Strong Acid, Weak Acid, Salt, and Buffer Solutions The purpose of the current experiment was to determine the pH of various hydrochloric acid and acetic acid solutions, to determine the pH of various salt solutions, to prepare a buffer solution, and determine the effects of adding a strong acid and strong base to the buffer solution versus adding a strong acid and strong base to water. The measured pHs for the hydrochloric acid solutions were 1.6, 2.2, 2.9, and 3.8. The measured…
-
Essay Determining the Ideal Gas Constant
652 Words | 3 Pages1 – Determining the Ideal Gas Constant Introduction: Finding and balancing equations to find the ideal gas constant using PV=nRT. Using Excel to format and graph various types of data, both given and calculated. The data given for the decomposition of NaHCO3 and Na2CO3 provided the information needed to determine the experimental constant “R” that can then be compared to the textbook definition of “R”. Experimental: Data was provided as “Experiment 1: Determining the Ideal Gas Constant”, see…
-
Mass Density Of An Unknown Metal
1066 Words | 5 PagesThe goal of this experiment was to determine the mass density of an unknown metal. Five different vernier capillaries and double pan balances were used to measure the metal. The plan of action was to find the average density to reduce random error, in addition to, calculating the standard error to observe the reliability of proposed average. Ideally, the metal would identify more comparably with gold or aluminum. The concepts of mass density, standard error, average, one-dimensional statistics…
-
The Ka and Molar Mass of a Monoprotic Weak Acid Essay
1676 Words | 7 Pagesand Molar Mass of a Monoprotic Weak Acid Chemistry Lab 152 Professor: James Giles November 7, 2012 Abstract: The purpose of this experiment was to determine the pKa, Ka, and molar mass of an unknown acid (#14). The pKa was found to be 3.88, the Ka was found to be 1.318 x 10 -4, and the molar mass was found to be 171.9 g/mol. Introduction Acids differ considerable as to their strength. The difference between weak and strong…
-
The Relative Formula Mass of an Unknown Acid Essay
1463 Words | 6 PagesThe Relative Formula Mass of an Unknown Acid Table of contents 1.1 Aim of the experiment 2 1.2 Introduction 2 1.3 Equipments and apparatus 2 1.4 Safety precautions 2 2.1 Procedure 3 2…
-
Identification of an Unknown Organic Acid Essay
2628 Words | 11 PagesIdentification of an Unknown Organic Acid Chem 1211K Lab Drawer #15 Wednesday November 13th, 2013 Unknown Number: 3334025-CF13 Table of Contents Pg. # Abstract 3 Experimental Report 4-7 Results and Discussion 7-12 Conclusion 13 **pKa Graph 14 Abstract Identifying this organic acid was an extensive task that involved several different experiments. Firstly, the melting…
-
Identification Of Unknown Amino Acid
3685 Words | 15 PagesIdentification of Unknown Amino Acid & Measurements of Buffer Capacity Student #: 998493250 Authors: Young, Lee & Melissa Abstract The titration curve of the unknown exhibited many characteristics, such as equivalence points, pKa of ionizable groups, isoelectric point, and buffer regions, that are particularly distinct to lysine. For unclear reasons, the pH during the titration did not reach the pH for pure 0.2 M NaOH nor 0.2 M HCl and normal equivalence points expected at two…
-
The Fischer Esterification Of An Unknown Acid
979 Words | 4 PagesFischer Esterification of an unknown acid and an unknown alcohol was used to prepare an unknown ester. Sulfuric acid was used as a catalyst in the reaction which then was put under reflux. After cooling, the pH of the solution was raised to approximately 8 using sodium carbonate. Diethyl ether was added, then the aqueous layer was removed and the organic layer was washed with sodium chloride. The aqueous layer was removed again and sodium sulfate was added. The unknown product was then identified…
More about Determining The Equivalent Mass And Dissociation Constant Of An Unknown Weak Acid
-
This is a chemistry lab report on an Acid-Base Titration experiment.
2714 Words | 11 Pages -
Synthesis of Salicylic Acid and Potentiometric Determination of Its Purity and Dissociation Constant
4209 Words | 17 Pages -
Studying the pH of Strong Acid, Weak Acid, Salt, and Buffer Solutions
1676 Words | 7 Pages -
Essay Determining the Ideal Gas Constant
652 Words | 3 Pages -
Mass Density Of An Unknown Metal
1066 Words | 5 Pages -
The Ka and Molar Mass of a Monoprotic Weak Acid Essay
1676 Words | 7 Pages -
The Relative Formula Mass of an Unknown Acid Essay
1463 Words | 6 Pages -
Identification of an Unknown Organic Acid Essay
2628 Words | 11 Pages -
Identification Of Unknown Amino Acid
3685 Words | 15 Pages -
The Fischer Esterification Of An Unknown Acid
979 Words | 4 Pages