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Essay On Soil Degradation In Soil

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From the findings of Roslev et al. (1998) [54], PAH degradation in soil most often follows first order kinetics which was chosen here to model the degradation . Modeled versus measured average values of selected PAHs using Eq. 1 is plotted in Fig. 5. Despite some scatter, measured and fitted values match relatively well with an average relative deviation of 21%. R2 values were within the limits of 70–97% at P < 0.01. Values obtained from the model are in correlation with the measured values and are grouped around the linear fit of the slope (Fig. 5.). It is evident that the model describe well the changes of concentrations of the contaminants.

Fig. 5. Correlation between actual (determined) concentrations of total soil PAHs and …show more content…

The average RMSE (%) of soil moisture for this study was 10.8%, whereas it was 21.3% and 19% for the Geng et al. [56] and Zhang et al. [57].

Fig 6. The degradation of four selected PAHs at the temperatures 10°C and 20°C showing measured and model results

5.3. Impact of rainfall on soil PAH degradation rates
Rainfall is useful in the biodegradation of soils by supplying moisture and useful dissolved oxygen to microbes for degradation of dissolved organic pollutants, such as PAHs [58]. Based on the model results, Fig. 7 shows the relationship between rainfall and the total PAH degradation rate in percentage for the three sites (W-01, W-02 and W-03) for two different years. The pattern of behavior of PAH degradation versus precipitation was as expected. In 2006 which recorded the highest precipitation, it can be seen from the model estimates that a higher percentage of PAH degradation is also observed. Overall, the study indicates that the modified DNDC model (DNDC-OP) is capable of capturing the major trends of pollutant degradation in soils for the different weather conditions located in Canada.

Fig. 7. Model results showing rainfall (mm) and percentage degradation of soil PAH at three sites: Ft. McMurray (W-01), Edmonton (W-02) and Red Deer (W-03).

5.4 Effect of soil temperature and soil moisture on soil PAH degradation rates
A scenario analysis was conducted to examine the influence of temperature and moisture on

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