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Graded Assignment: Chemistry

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Name: Date:
Graded Assignment
Unit Test, Part 2
Answer the questions below. Unless otherwise instructed, you may use a scientific calculator for this test. When you have finished, submit this assignment to your teacher by the due date for full credit.
(5 points)
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1. Nitroglycerine (C3H5(NO3)) is a powerful explosive. The products of this reaction are elemental oxygen, elemental nitrogen, water, and carbon dioxide. The Gibbs free energy for this reaction is negative at 273 K. Determine whether the reaction is spontaneous.
Answer:

Because the Gibbs free energy of this reaction is negative, this is a spontaneous reaction. In addition, it is an exothermic reaction and gives off energy (explosion) and the reaction products are the result of the break down of Nitroglycerine, in other words, the entropy of the …show more content…

As a result, this reaction is spontaneous at all temperatures.

(8 points)
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2. Consider the following reaction occurring in a closed chemical system. Assume that this reaction is at equilibrium and that in general the reaction to the right is favored.
CaCO3 (s) + 2HCL (g) CaCl2 (s) + H2O (l) + CO2 (g) ∆H = –90 kJ/mol
• What type of chemical reaction is this?
Exothermic
• If more CaCO3 is added to the system, how will the reactions shift to reach equilibrium again?
Increasing the concentration of CaCO3 will shift the equilibrium towards the products (right)
• If water is extracted from the system, how will the reactions shift to reach equilibrium again?
If water is extracted, the reaction will shift the equilibrium to the products (right)
• If heat is removed from the system, how will the reactions shift to reach equilibrium again?
The reaction will shift the equilibrium to the right to produce more heat.
• What is the name of the principle that helps predict each of these shifts in equilibrium?
Le Chatelier’s Principle

(8 points)

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