Investigation to Find the Relative Energy Release of Five Alcohols: Ethanol, Methanol, Propanol, Butanol and Propanol
Aim:
In this experiment I will investigate to see which alcohol releases the most energy during combustion; Methanol, Ethanol, Propanol,
Butanol or Pentanol.
Hypothesis:
I think that the alcohols with the longest carbon chains will release the most energy. This is because when a bond is broken energy is released. This means that the alcohols with longer chains and therefore more bonds will release more energy. This will mean they will heat the water quickest. This should mean that Pentanol will heat the water by the largest mount in 5 minutes. However, because of the longer hydrocarbon chains and therefore more bonds,
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This proves my theory that the hydrocarbon with the longest carbon chain will release the most energy because it has a larger number of bonds than the other four alcohols in this investigation.
Preliminary Work:
Before I completed my experiment I completed some preliminary investigations. I completed an experiment to decide several potential variables within the final experiment. These include:
Ø The apparatus I will use in the final experiment (clamps, clam stands)
Ø The height the tin containing the water is away from the flame
Ø The amount of water
Ø The type of tin (percentage steel etc)
Ø Where the water comes from
I will burn three of the five alcohols: Ethanol, Propanol and Butanol.
Although I have tried the experiment with 50cm3 and 150cm3 of water I felt that 100cm3 was the better amount. I also tried different periods of time but I chose five minutes because it was the one which did not take too long, but allowed the water to be heated sufficiently for the experiment. I also tried different heights that the tin should be from the flame but I decided that 15cm would be the best choice as it allowed the heat to reach the tin, but wasn’t too low. I will use
100cm3 of water in a normal tin picked at random which will be used for all of the experiments.
For this preliminary work I only burnt Ethanol, Propanol and Butanol to get an
idea, rather
The aim of the experiment was to find out how changing the mass effects the rise of the temperature of water.
Methanol, ethanol, 1-propanol, and 1-butanol are alcohols that contain both London-dispersion forces and hydrogen bonds. Hydrogen
alcohol, making it either primary (1° ), secondary (2° ), or tertiary (3° ). If the OH is bonded to only one other carbon, it is a primary alcohol (eg. 1-butanol); if bonded to two other carbons, it is a secondary alcohol (eg. 2-butanol); if bonded to three other carbons, it is a tertiary alcohol (eg. 2-methyl-2-propanol). Due to the placement of the hydroxyl functional group in each of the degrees of alcohol, the reactivity of each should be impacted. This means that all three
The Hydroxyl group on alcohols relates to their reactivity. This concept was explored by answering the question “Does each alcohol undergo halogenation and controlled oxidation?” . Using three isomers of butanol; the primary 1-butanol, the secondary 2-butanol and the tertiary 2-methyl-2-propanol, also referred to as T-butanol, two experiments were performed to test the capabilities of the alcohols. When mixed with hydrochloric acid in a glass test tube, the primary alcohol and secondary alcohols were expected to halogenate, however the secondary and tertiary ended up doing so. This may have been because of the orientation of the Hydroxyl group when butanol is in a different
Of the alcohols tested 1-Butanol was found to contain the strongest intermolecular forces (IMF) of attraction, with Methanol containing the weakest. It was discovered through experimentation that Methanol induced the highest ?T of all alcohols tested, and that conversely 1-Butanol induced the lowest ?T. The atomic structure of all four alcohols is very similar, as starting with 1-Butanol a CH2 group is lost as you move from 1-Butanol to 1-Propanol to Ethanol and then again to Methanol. Each structure is fairly linear and contains an H-bond with Oxygen, so the real change is found in the loss of the CH2 group, this lowers the liquid’s Molecular Mass, thus lowering the London forces as you move from 1-Butanol through
Planning My aim for this experiment is to see the energy produced from different alcohols. This investigation involves burning alcohol in the air. ‘GCSE Chemistry’ by B.Earl and L.D.R Wilford says that "alcohols form, another homologous series, with the general formula Cn H2n+1OH ". The alcohol reacts with the oxygen in the air to form the products water and carbon dioxide.
Alcohol dehydrations are widely used in many industries to produce alkene. In this experiment 2-methylcyclohexanol was dehydrated to three possible products using phosphoric acid as a catalyst. The main tool for this experiment is the Hickman still. First, Drierite was added to the Hickman still so that any excess water formed during the experiment will be absorbed. It also acted as a boiling stone and addition surface to increase surface area. Next, 0.75 mL of 2-methylcyclohexanol is added to the still and right after 1 mL of phosphoric acid is added. The phosphoric acid (H3PO4) acts as a catalyst in order for the reaction to occur. The mixture is heated up to between 120o Celsius and 160o Celsius. If the temperature goes above 165oC then
B. Claim: As we go from methanol ethanol 1-propanol 1-butanol the dispersion forces increase.
By default, interval time is set to `1` second. But you can define the custom
The experiment began by mixing the initial 1.775g isopentyl alcohol with 2.3 mL acetic acid and about 5 drops sulfuric acid. This reaction mixture was then heated under reflux for an hour after boiling of the reaction mixture began.
The dehydration of 2-methyl-2-butanol was performed using sulfuric acid and phosphoric acid in order to synthesize alkene products 2-methyl-1-butene and 2-methyl-2-butene. After carrying out steam distillation to isolate the organic alkenes from aqueous components within the reaction mixture, the purity and characterization of the products were then assessed through various analytical methods including Gas Chromatography (GC), Infrared Radiation (IR) Spectroscopy, and Nuclear Magnetic Resonance (NMR) Imaging. Through the characterization of the final products, it was found that little impurities remained in the final reaction solution and according to the GC, no alcohol remained in the vial after the reaction was complete. The actual yield
For instance, pentan-1-ol, the alcohol utilised to synthesis 1-pentyl ethanoate, is relatively flammable due to the hydroxyl functional group attached to the molecule. Therefore, in order to prevent severe burns, a laboratory coat and safety glasses were worn. The experiment was additionally performed whilst standing up, so that if the aliquot of pentan-1-ol ignited,
A 10 mL round-bottom flask was weighed both before and after approximately 1.5 mL of the given alcohol, 4-methyl-2-pentanol, was added. 3 mL of glacial acetic acid, one boiling chip, and 2-3 drops of concentrated sulfuric acid were added to the flask in that order. The reflux apparatus was assembled, the
Before the start of the experiment, the theoretical yield was to be calculated. First, the limiting reagent was determined from the reagents by comparing the amount of moles. Among the three reagents involved in this experiment - camphor, sodium borohydride, and methanol, camphor was found to be the limiting reagent. The moles of camphor was less than the combined moles of the other two reagents. The theoretical yield, which is the amount of product that could be possibly produced after the completion of a reaction (“Calculating Theoretical and Percent Yield”), was found to be 0.25 g. Once the product was achieved, a percent yield of 97% was determined. As a result, the reduction of camphor to isoborneol was successful.
The results that were revealed were thought to be accurate and reliable as many factors were controlled to enable the best quality. The results that a constant rise in the combustion occurred as each alcohol’s carbon chain increased with one exception indicates that the reliability of this experiment has to be examined. With such a high percentage error from these results means they cant be definitive. Also only three trials were conducted on the five different alcohols. If the experiment were to be conducted again I would conduct five trials on each alcohol to get a better average.