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Lab Report On Solid Oxide Fuel Cells ( Sofc )

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Abstract
In order to decrease the number of cycles of infiltration and maintain a comparable cathode performance, the viability of using a conductive LSF-YSZ composite scaffold with one infiltration cycle of LSCF was investigated. XRD patterns of LSF-YSZ powder presented that at 1400oC and 1300oC calcination, an obvious shift in LSF peak occurred, indicating Zr doping into LSF and forming a less conductive phase. Different ratios of LSF-YSZ scaffolds were tested by impedance spectroscopy with the results showing that the ohmic resistance decreases as the amount of LSF increases, and 1350oC scaffold has a much lower ohmic resistance than the 1400oC one. A pure YSZ cell infiltrated with 35 wt% LSCF was used as reference and by comparing it with a cell composed of 70:30 LSF-YSZ scaffold calcined at 1350oC with one cycle of LSCF infiltration, a comparable cell performance both in ohmic and non-ohmic parts was achieved.
Introduction
In solid-oxide fuel cells (SOFC), the typical cathodes with the best performance are usually composites of the electrolyte oxide and an electronically conductive and catalytically active oxide which is usually a perovskite.1,2 For example, in cells made of yttria-stablized zirconia (YSZ) electrolyte, the conventional cathode composite is a mixture of YSZ and Sr-doped LaMnO3 (LSM). 1,2 The commonly used YSZ electrolyte oxide in the electrode is to enhance the ionic conductivity, thus increasing the electrochemically active region in the electrode. 1-4

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