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Methanol: Ecologically Clean Fuel

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In recent years increasing interest to methanol as an effective means to produce a ecologically clean fuel, available and cheap raw materials for the synthesis of various hydrocarbons and products of their processing. The most accessible and cheap raw material for the obtaining of CH3OH are natural and associated gases, from which by Fischer-Tropta's method it is possible to obtain hydrocarbons of different composition and structure. The formation of gasoline from methanol, developed in the present time flows through the stage of formation of DME, which turns further into the mixture of hydrocarbons consisting more than 50% of the valuable branched paraffins. Such "methanol" fuel in their composition does not contain sulfur and nitrogen compounds and a minor amount of aromatic compounds. Now, methanol increasingly became used as fuel and also as additives to motor fuels (from 3 to 65%). Methanol increases the octane level of fuels and reduces harmful emissions into the atmosphere. Based on the methanol it is possible to obtain alternative pollution-free fuels such as dimethyl ether (DME) and dimethoxymethane (DMM). Dimethylether is used as pollution-free diesel fuel contains no sulphur, and …show more content…

Samples of catalysts pre-treated with solutions of its salts washed, dried, and activated, then loaded in a quartz reactor, which was supplied a mixture of methanol and air. The reaction was performed at T 413–573К. The reaction products were analyzed by chromatography, the yield of DME on natural clinoptilolite made 24.1%, for Cu2+– modified sample is 47.7%, of Co2+ – modified sample is 41.3%. The introduction of relatively small amounts of cations Cu2+, Co2+ led to increase of catalyst activity. Influence of partial pressure of CH3OH on the yield of DME is studied (max output of DME is achieved at a ratio of CH3OH:O2=

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