Rate Law Lab

3. Carefully felt the sides of the test tube and observed the resulted chemical reaction for about 30 seconds.

During the immersion of the magnesium metal in the hydrochloric acid solution, white bubbles could be seen escaping the surface of the metal as gas was produced during the reaction. Depending on the temperature of the hydrochloric acid and the overall molar concentration, the rate of reaction differed but the same signs were shown. During the reaction between the magnesium metal and higher concentrations of hydrochloric acid, it was observed that the test tube grew quite warm to the touch. As the immersed magnesium strip sank down, it appeared coated in a layer of white bubbles that fizzed like a carbonated drink. In the lower concentrations of hydrochloric acid, the strip spent some time floating at the surface of the solution in the test tube, later sinking down to the bottom as the

The purpose of this lab was to test the law of definite proportions for the synthesis reaction of combusting magnesium. In this lab, the polished magnesium ribbon was placed in covered crucible and was heated in order for it to react with Oxygen presented in air and in water provided. The result showed that Magnesium oxide formed through chemical reaction was made up of 60.19% magnesium and 39.81% oxygen, which is approximate proportion of both particles in every Magnesium oxide compound. From this lab it can be concluded that the law of definite proportion stating that the elements in a pure compound combine in definite proportion to each other is factual.

    In this lab, a calorimeter was used to find the enthalpy of reaction for two reactions, the first was between magnesium and 1 molar hydrochloric acid, and the second was between magnesium oxide and 1 molar hydrochloric acid. After the enthalpy for both of these were found, Hess’ law was used to find the molar enthalpy of combustion of magnesium, using the enthalpies for the two previous reactions and the enthalpy of formation for water. The enthalpy of reaction for the magnesium + hydrochloric acid reaction was found to be -812.76 kJ. The enthalpy of reaction for the magnesium oxide + hydrochloric acid reaction was found to be -111.06 kJ. These two enthalpies and the enthalpy of formation for water were manipulated and added together using Hess’s law to get the molar enthalpy of combustion of magnesium. It was found that the molar enthalpy of combustion of magnesium was -987.5 kJ/mol. The accepted enthalpy was -601.6 kJ/mol, which means that there is a percent difference of 64%. This percent difference is very high which indicates that this type of experiment is very inefficient for finding the molar enthalpy of combustion of magnesium. Most likely, a there are many errors in this simple calorimeter experiment that make it inefficient for finding the molar enthalpy of combustion of magnesium.

Kinetics is the study of the rate of chemical processes. The kinetics of the reaction between crystal violet and NaOH was studied. In order to monitor crystal violet concentration as a function of time, a spectroscopic colorimeter was used. What is the rate law for decolorization of crystal violet? In order to figure this out, the rate of the reaction of crystal violet and sodium hydroxide must be found. In this experiment, the initial goals were to determine the overall rate law for the rate of decolorization of crystal violet in basic solutions as a function of time and to determine the rate law for the reaction including the actual value of k; Rate = k[A]x[B]y. The rate of a reaction was expected to depend on the concentrations

I could use a gas syringe to collect the gas that will evolve from my

About 80 mL of HCl was obtained and mixed with phenolphthalein. Using a LabQuest unit and Gas Pressure Sensor kit, the HCl mixture was added to the flask with the magnesium ribbon and allowed to react. When reaction was complete, the change of temperature and gas was recorded. This procedure was repeated for different masses of magnesium ribbon (masses found on page 89 of the lab manual). After the completed procedure, moles of H₂ produced in each trial were calculated. (The actual procedure can be found on pages 87-89 of the lab manual)

It had a lot to do with the time and the amount of oxygen evolved. When holding the leveling bulb it seemed that the longer I had to hold it level the harder it became to be as accurate. I would find my arm getting tired and the bulb varying, which would also effect the times that we recorded. Another thing that could have affected our results was not putting the stopper on the Erlenmeyer flask fast enough, fumes from the formation of oxygen could have escaped before we got the stopper on, causing error in the amount and time in which the oxygen was evolved.

In the second experiment, a reaction between magnesium and hydrogen chloride was used to produce hydrogen gas, whose volume was measured using a collection over water. Using this method, it was found that the resultant hydrogen gas had a volume

The term concentration refers to the amount of a substance present in a certain volume of liquid or gas. Increasing the concentration of the reactants will increase the rate of the reaction. If the concentration of a reactant in a solution is increased, there will be a greater number of particles in a given volume of solution. This means the particles are more likely to collide and therefore react when there are more of them. Collisions between particles are necessary for the reactants to rearrange and form the products. In this experiment, the rate of the reaction between magnesium ribbon and hydrochloric acid will be increased by adding a higher concentration of hydrochloric acid each time. The chemical equation between magnesium ribbon and hydrochloric acid can be written as:

The volume of carbon dioxide gas produced from a reaction was measured in order to determine what carbonate sample was used. A gas assembly apparatus was used to capture the gas from a reaction between an unknown carbonate and 6M hydrochloric acid; three trials were performed. The mass of the unknown carbonate was determined, and the reaction occurred in a test tube. The volume of gas produced by the reaction was measured, and the partial pressure of carbon dioxide was calculated after the partial pressure of water vapor was determined using Dalton’s Law of Partial Pressures. The percent mass of carbon dioxide gas was then calculated, and the average mass percent was compared to the table of known carbonates. It was concluded that the unknown carbonate sample used in the reaction was magnesium carbonate.

Science Coursework – What factors effect the rate of reaction between magnesium and hydrochloric acid? Background Knowledge There are four factors that can affect the rate of reaction and they all rely on the collision theory. This is basically how hard and how often particles collide with each other. The more and harder they collide, the faster the reaction time will be.

Overall, the results were almost as expected. It was predicted that Magnesium and Calcium would have a similar reaction will the hydrochloric acid and produce approximately that same quantity of hydrogen gas. However, the results demonstrated that the Calcium reacted more vigorously than expected and produced a larger quantity of hydrogen gas. The reaction which occurred whilst using Magnesium resulted exactly like the prediction. It was expected that the metal would bubble, eventually dissolve and produce gas which would potentially displace the water in the test tube. With the reaction involving Calcium, it was not predicted that it would heat up the conical flask and react as violently. It was expected that the Tin would either have a

In order to find the molar volume of a gas at standard temperature and pressure (STP), one could create a reaction between a magnesium (Mg) ribbon and excess hydrochloric acid (HCl). By having HCl put into a eudiometer tube, then adding DI water nearly to the brim, one can then add Mg, by means of a copper wire cage attached to the tube stopper. The tube thereafter, is inverted and directly put into a bath of water. Due to HCl’s greater density than water, HCl will move down to the now-bottom of the eudiometer tube and react with the Mg ribbon. The reaction yields liquid magnesium chloride (MgCl2)and hydrogen gas (H2); the gas particles of H2 will then move to the top of the tube, where it is trapped.

Experiment to investigate factors affecting the rate of reaction between magnesium ribbon and hydrochloric acid