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The Importance Of The Conversion Of Lower Energy Light

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Upconversion is a term that characterizes the conversion of lower-energy light, particularly in the near-infrared region, into higher-energy light within the visible spectrum. This occurs through a process in which the sequential absorption of multi-photon near-infrared light yields the emission of light that is of shorter wavelength[1]. This process is represented in Figure 1, which shows the emissions of light within the visible spectrum after excitation of various dopant ions by near-infrared light[1]. The upconversion effect has been observed primarily in the rare-earth metals of the lanthanides as well as yttrium, and scandium; however, some transition metals and actinides can also display this effect[2]. Lanthanide ions display special inner-shell arrangements of 4fn 5d0-1, which allow for unique energy levels and provide shielding from the outer shells[2]. Due to their various f-orbital configurations, lanthanide ions are able to display very sharp luminescence emissions via intra-4f or 4f-4d transitions[2,3]. The importance of the lanthanide ions is evident in several applications including applications in lasers, bioprobe applications, optical imaging, and photodynamic therapy [2,3]. This is due to their fluorescent properties, which include: resistance to photobleaching, monochromaticity, large Stokes shifts, narrow bandwidth, and long emission lifetime[2,3]. The direct excitation of the lanthanide ions is not very effective because they are limited by low

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