. The following data were obtained for the gas phase decomposition of nitrogen dioxide at 300 oC,                                            NO2(g)                      NO(g)   + ½ O2   Time (sec) 0 5 10 20 30 NO2  Pressure(atms) 0.1 0.0787 0.0649 0.0481 0.0380     NOTICE: We can use pressure as a unit of concentration for a gas since we know from the ideal gas law that the pressure is directly proportional to the number of moles per unit volume. Determine the order of the reaction with respect to NO2 Determine the value of the rate constant (K).

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Kinetic-Theory of Gases

Kinetic theory of gases is the model or method which was developed in the 19th century by Maxwell and Boltzmann. This is possible as the interatomic force which is of short-range forces that are important for solids and liquids can be neglected for gases. This theory or gas law gives a molecular interpretation of the pressure and temperature of a gas and is consistent with gas laws and Avogadro’s hypothesis. This theory is very helpful to correctly explain the specific heat capacities of many gases, kinetic energy and it also explains the transport qualities such as viscosity, thermal conductivity, and diffusion with molecular parameters. As stated in the kinetic-molecular theory, the temperature of a substance or gas particle is related to the average kinetic energy of the particles of that substance. When a substance is heated, some of the absorbed energy is stored within the particles, while some of the energy increases the motion of the particles, called average kinetic energy.