Please answer subparts d and e Predict the major products of the following reactions. If it is possible, write all stereoisomers.(1) NANHa)H20d)(2)PhCH,Br(3) HNIB (P-2)H2S04b)Br2e)03(1) BH3 THFc)(2) NaOH, H20

In reaction 1st the alkyne is treated with base NaNH2 to abstract the hydrogen. The sodium salt so…

Answered: (1) NaNH d) (2)PHCH Br (3) HNi,B (P-2)…

Science

Chemistry

(1) NaNH d) (2)PHCH Br (3) HNi,B (P-2) e) 03

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter17: Alcohols And Phenols

Section17.SE: Something Extra

Problem 24VC: Name and assign R or S stereochemistry to the product(s) you would obtain by reaction of the...

See similar textbooks

Related questions

Q: d- Explain why Piperidine is more basic than pyridine about 10 `N H кь - 1 х 103 2.5 x 10 Kb %3D

A: According to Lewis theory of acid and base, a base is defined as a molecule which can donate its…

Q: NaOH(trace) a). CHO H20 HCltrace) b). H20 c). NaOH trace) H20

Q: РОСЬ, Ме2N.CНО SO3, Pyridine PhN2 CI aq. KOH N-Chlorosuccinimide, H MEOH or NaOCI, base…

Q: Is this the correct way that the mechanism works?

A: Structure of indole is given below.

Q: e basic anions?

A: This is a multiple questions. According to guidelines in multiple questions, we can solve only the…

Q: 6.51

A: The bio-synthetic route is shown below

Q: `Me 1) excess Me-I N. Me 2) 60% NaOH; acidic work-up Ме NH2

Q: N-Substituted morpholines are building blocks in many drugs. Show how to synthesize…

A: The actual synthesis of N-methylmpholine from the given retrosynthetic analysis is to be drawn.…

Q: um what is the Mechanis. 2% NaOH Me Me Me ELOH Me 94:6 P.M. McCurmy Ir Chamistry 1974, 39, 2316

Q: (o-p) (q-r) cold KMnO4 HCI 1.03 2. H*, Zn 1. BH3 2. H₂O₂, OH

A: When ozone is used in an organic chemical reaction to break the unsaturated bonds in alkenes,…

Q: Which side of the 0.085 M AGCIO4|0.085 M KCIO4 junction will be positive? O AgCIO4 O KCIO4

A: Liquid junction potential occurs when two solutions of electrolytes of different concentrations are…

Q: Fill in the product that goes in the yellow box 1452 End 63% yed + MezNOH psiMes Bno osSiMes Brom…

Q: Reaction Mechaniem Mgbr OH -ATHY 2. 3. - OH, Y + OH 4 OH VOH 5 Y t HO DH

Q: Which of the following will give a negative result with Br2/CCI4? O a) O b) O d) H. Which of the…

A: Br2 in the solvent of CCl4 give addition reaction on alkene and alkyne ( called trans addition…

Q: R - NH2 NH. HO NH DCC,THF NH RT, N2 (atm.) Вос `NH2 Вос `NH2 6(b-e) R= -CH,CH(CH,),.(2b) -CH,Ph,(2e)…

A: The reaction involves deprotection of amine group and results in formation of desired heterocyclic…

Q: Treatment of indene with NaNH2 forms its conjugate base in a Brønsted– Lowry acid–base reaction.…

Q: Rank the following groups in order of decreasing priority: A.-COOH В.-Н C.-NH, D. -OH А В C D…

A: According to the CIP rule, the first attachment to chiral carbon will be assigned priority according…

Q: LOD NH 500 L000 4 D00 3000 2000 1500 HAVENUMB ERI 1l 50 4 D00 3000 2000 15 00 1000 5 DO HAVENUMB ERI…

A: IR spectroscopy helps us to find the functional group in the given compounds .

Q: `NH H*

Q: Aa - =、而、前、 T A:

A: Dear student I have given answer to your question in the image format.

Q: HO- 나 E1/E2 rcaction

Q: А. Br- Pd(OAc)2 HO. P(0-tolyl)3 (CH3CH2)3N Br Pd(OAc)2 P(0-tolyl)3 (CH3CH2)3N Br. OH HN. mou HO, HN…

Q: 13. Even if you do not know the exact pk, values, circle the side favored by equilibrium in the…

Q: HN (p) HN HN Но () (9) (e) 6.44. Identify the most basic site. 00

Q: The synthesis of an azo dye is shown below. Please answer the following questions. NH2 N2 1) NażCO3…

A: In this question, we will see which nitrogen is most basic Nitrogen in Compound - 3 You can see…

Q: Br Br TMS CI он 6-Brom o-naphth alen-2-ol TMS O CH3 H3C CEN MgBr Br TMS O TMS O CH3 COOH но Naproxen…

A: Naproxen is an anti-inflammatory drug used to treat pain and inflammatory diseases such as…

Q: Rank the leaving groups below from worst to best. 5th attempt l See Period Question List (5 items)…

Q: What arethe reagents needed to complete this reaction? a. Hz/ Lindlar's cataly st b. Li, E+NH2,-78°…

A: Welcome to bartleby ! We have to tell the appropriate reagent for the above transformation .

Q: Al a. b. BF3 С. H20 -

A: organic

Q: Select Draw Rings More Erase C H P 1 CH3CH2OH Но -OH + H20 но — р — он OH он Select Draw Rings More…

A: Given data :-

Q: 5) N-Methylbenzylamine CSHIN MW = 121.18 100 120 80 91 60 121 40 77 20 * 9 8 8 8 8 9 messicharge…

Q: over Short Answer 2. 3. Rank the following molecules from most acidic (1) to least acidic (4) (ень…

Q: CH3OH/H Na NaCN/H,O 2 H₂O LIAIH4 1. CH₂MgBr 2. H₂O H₂O/H30* CH3ONa CH3OH_ NH3

A: Acidic condition -----> Nucleophile attacks on the greater substituted site of epoxide Basic…

Q: COMe NH 28 OBn ŌBn 1) p-TSOH, benzene, reflux 2) amine (1 eq), benzene, reflux Bno-T OHC Br 25 OBn…

A: The given reaction involves multiple steps in which various mechanisms are applicable. The product…

Q: Calculale at tte e9uiualen a Dont o hen 1s tetrated hy 2S. OmL Or 8. 2.S.0mL loomat {thrकएd lo0m HCI

A: The balanced reaction and moles of ammonia in initial solution can be given as follows:

Q: Hypervalent iodine reagent OH Br ? THE Br 1.00 eq. 2.00 eq. please consider that there are 2 eq of…

A: In this question, we will write the major product of this reaction. You can see below.

Q: Complete the reaction map by matching A-E with the given choices. H2 H2 A B E Pt Cl. Na in lig NH3 D…

A: Reaction map from A to E shown below

Q: Н. H Н Н Н HICT :Z-T Н

Q: 3. What happens when you treat unknown molecule A with lithium aluminum hydride (LIAIH.) and then…

A: Consider CH3CN is the substrate and whenever this is treated with LiAlH4 followed by Acidic…

Q: IR order of decreasing acidity. OH> HO, HO, H-CO H3C .జ ఒప ఎంగడిలక క- OH > HO. HO. он O2N H3CO H3C…

Q: im

A: step 1

Q: 2. Give the wet chemcial tests (#1-6) that work for ALDEHYDES onl the p urnec e of m aking aa "d…

A: Aldehydes can be identified by using Fehling's solution, Benedict 's solution, Tollens' s reagent.

Q: what is the best mpound to make X o Give mechamism? compound OH (b) BY BY Br Nat

Q: B-H

A: Aromatic compounds are those which follows (4n+2) π huckel rule. If n = 0, 2π n = 1,.…

Q: Continue the following reactions: A P(CH3)3 Hf P(CH3)3 B Pt

A: The arrangement of the groups such as ligands around the transition metal ion furnishes the…

Q: 3. Complete the reactions below: CH OH thium aluminium hydride PCC (excess) Tollen's Reagent A1 > A2…

A: PCC is mild oxidising agent, tollen reagent oxidised aldehyde group and lithium aluminium hydride is…

Q: Aniline C6H5NH2 has a base dissociation constant (Kb) of 4.3 × 10-10. What is the conjugate acid of…

Q: 4.1. Acidic enolization use the correct arrow ( rerorsible/ irrwersible ) Hy POg *o-H H H. conjugate…

Q: Provide c mechgnism dit > Br HO Br TOOH It

A: This reaction is used to protect aldehyde and ketone from some reaction . This type of reaction is…

Q: Hello, can you list the basicities from large to small with reasons? a) Aniline b) Pyridine c)…

A: The structures for the given bases are as follows: The base is an electron pair donor. Greater the…

Question

Please answer subparts d and e

Predict the major products of the following reactions. If it is possible, write all stereoisomers.
(1) NANH
a)
H20
d)
(2)PhCH,Br
(3) HNIB (P-2)
H2S04
b)
Br2
e)
03
(1) BH3 THF
c)
(2) NaOH, H20

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Propose a plausible mechanism for the 1 to 2 conversion as shown, and explain the stereochemical result:
predict the major product of the reaction sequence below and how many stereoisomers of the major product would be produced
Predict the major products of the following reactions. Include stereochemistry whereapplicable.(a) 1@methylcycloheptene + BH3 # THF, then H2O2, OH-(b) trans@4,4@dimethylpent@2@ene + BH3 # THF, then H2O2, OH
Draw mechanism arrows and then predict the major products and stereochemistry. Also include the labels of thermodynamic and kinetic 1-methylcyclohexene with BH3 followed later with –OH, H2O2, and H2O.
What will be the resulting organic products’ structure when the following reactions occur and determine the mechanism (SN1, SN2, E1 or E2)? (R)-2-iodobutane reacts with NaOCH3 (show proper stereochemistry of product)
The isomer of 1,2,3,4,5,6-hexachlorocyclohexane shown undergoes E2 elimination 7000 times more slowly than any of its steroisomers. Explain this observation.
predict the major product of the reaction sequence below and how many stereoisomers would be produced
Predict the major products of the following reactions. Include stereochemistry whereapplicable.(a) 1@methylcycloheptene + BH3 # THF, then H2O2, OH
Predict the major products when the following compounds are irradiated by light and treated with (1) 1 equivalent of Br2 and (2) excess Br2.(a) isopropylbenzene
Which of the following is/are the expected product/s of the reaction of 2-pentanone (CH3COCH2CH2CH3) with excess Br2, followed by OH-? CHBr3 + CH3CH2CH2COOH BrCH2COCH2CH2CH3 CHBr3 + CH3CH2CH2COO- CH3COCHBrCH2CH3
Doxaprost, an orally active bronchodilator patterned after the natural prostaglandins , is synthesized in the following series of reactions starting with ethyl 2-oxocyclopentanecarboxylate. Except for the Nef reaction in Step 8, we have seen examples of all other types of reactions involved in this synthesis. Q. Assuming that the two side chains on the cyclopentanone ring are trans, how many stereoisomers are possible from this synthetic sequence?
Give the structure of the possible clasein condensation product from the following reaction. Tell which ,if any you would expect to predominate in each case. (a)CH3CO2Et+CH3CH2CO2Et (b)C6H6CO2Et + C6H5CH2CO2Et (c)EtOCO2Et +Cyclohexanones (d)C6H5CHo +CH3CO2Et