1) What role do the protons play in the transformation of [(SALEN)VO] to [(SALEN)Cl2]?  --- Consider the number of anionic charges for all the ligands as well as the charge of the overall complex. Has the oxidation of vanadium changed in this reaction?

Q: Provide a name for the following complex ion:[AuF4]^-

A: Naming an inorganic complex ionRules to follow,Name all the ligands first in alphabetical order and…

Q: 7) If you were to use a ligand L that was a stronger field ligand than NH3, what color would you…

A: Step : 1             The required answer is follows as :

Q: k) The reactions of Group I and Group II with ammonia and chloride ligands give distinctly different…

A: Group I and group II elements are alkali or alkaline earth metals with valency +1 and+2…

Q: drow the electronic configuration of iron in heme part of hemoglobine knowing that it is a complex…

A:

Q: A transition metal, M, is coordinated in an octahedral fashion to the following ligands Two chloro…

A: We get a total of 6 Isomers.2 isomers where Cl atoms are trans.Since a sigma plane passes through…

Q: Explain in detail π backbonding using the molecular orbitals of CO and a d-transition metal. How…

A:

Q: Explain the following observations : Zn2+ salts are colourless.

A: The reason for Zn2+ salts are colourless has to be given.

Q: Question attached

A: All coordination complexes show 18 electron rule.

Q: 4. Many transition metal complexes are said to follow the "18-electron rule," meaning they form…

A: The molecular orbital is used to show the availability of electrons in the bonding orbitals,…

Q: Which of the following is most likely to bond to Ni2+ as a ligand?  Explain.   CH3-CH2-CH3…

A: The answer is given as follows

Q: Why are multidentate ligands preferable to unidentate ligands for complexometric titrations?

A: Ligands are generally negatively charged or neutral species with a lone pair that forms bonds with a…

Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1. Linkage…

A: Linkage isomer :-       It is a isomer of coordination compound,  in which ambidentate ligands have…

Q: In the octahedral field, dx2-v2 and d,2 are denoted as e, orbitals with the s-symmetry while dxy,…

A: In octahedral field, the molecular orbital diagram in different kind of ligand is different.…

Q: Explain the difference between double salt and metal complexes with examples?

A:

Q: Generally speaking, for a given metal and ligand, the stability of a coordination compound is…

A: The coordination complex consists of a central metal atom and a ligand bonded together by…

Q: Werner prepared two compounds by heating a solution of PtCl₂ with triethyl phosphine, P(C₂H₅)₃,…

A: From given percentage values the moles of each element is calculated as shown below, Pt moles=38.8g…

Q: 1 R3P" d. Consider complex 1. i. Draw a molecular orbital (MO) energy level diagram to describe the…

A:

Q: Define the ambidentate ligand and give two examples.

A: Those ligand which can donate electrons from two different atom site but donate from 1 site at one…

Q: Explain why the tetrahedral complexes A and B have magnetic moments of 1.89 and 0.0 BM respectively

A: Fe2+ is 3d6 It Has 0 unpaired electron in l.s. complexes and thus the magnetic moment would be close…

Q: Why d7,d8,d9 complexes prefer square planar with pi acceptor strong field ligands

A: Ligands are those species which forms a bond with metal by donating the electrons. Pi acceptor…

Q: How do I indicate ligand charge, metal oxidation states and electron contributions from ligands/…

A:

Q: Suppose that rather than reacting copper(II) with ammonia, you had reacted it with an ammonium salt,…

A: • It is given that rather than reacting copper(ll) with ammonia, one had reacted copper(Il) with an…

Q: What do you understand by ‘denticity of a ligand’?

A: Introduction: In a coordination compounds, ligand donate electrons to the central metal atom to form…

Q: a) Trialkylphosphine and ammonia are both strong-field ligands. However, experimental data show that…

A: Solution for a, PR3 ligands cause higher Δo than the NH3 because PR3 is σ-donor as well as…

Q: In [Ni(DMG)2], is DMG a chelating ligands and what is the type of this ligand depend on the number…

A: The type of ligand is depends upon number of donor sites by ligand to the central metal ion.

Q: Inorganic Chemistry (i) Define spectrochemical series (ii) Explain the difference between…

A: Given  Name of series = spectrochemical series  Definition = ? Weak field ligand  = ? strong field…

Q: drow the electronic configuration of iron in heme part of hemoglobine knowing that it is a complex…

A: Hemoglobin exist in two forms oxy hemoglobin and deoxyhemoglobin. In deoxy form oxygen will not bind…

Q: he magnitude of delta octahedral (A.) epends on: he nature and charge of metal and whether the hetal…

A: The question is based on the concept of coordination compounds. We have to identify the factors on…

Q: 1) Why are lanthanide  complexes always weak field in nature , second and third d-transition metal…

A: Hey, since there are multiple questions posted, we will answer first question. If you want any…

Q: Why is pyridine referred to as a monodentate ligand?

A: The structure of pyridine is given as

Q: Sketch structure of Mo(DMe) Cl2 (NMe,)2 , thhen apply ean to this complex showing ligand analysis…

A: The given chemical formula is: Mo(DMe) Cl2 (NMe)2 Assuming that DMe is OMe (methoxy group). The new…

Q: For each of the following pairs of complexes, which is least likely to undergo b-hydride…

A: beta-H elimenation recation occurs when there is any beta-H present in the co-ordinated ligand with…

Q: Why is the pH of the medium important for the formation of chelated complexes between metal ions and…

A: pH is the negative logarithm of hydronium ion and its measure the acidic and basic nature of…

Q: 9. Describe the various ligand classes and give an example in each case! 10. Justify why…

A: Ligand is atom or ion which donate electron density to metal ion.

Q: Consider the shown crystal-field splitting diagrams (Figure 1). Select the one that fits each of the…

A: Answer

Q: 2. It was stated that Co3+ complexes are very stable and the ligands in such complexes are not…

A:

Q: Will methylamine (CH3NH2) be a monodentate or abidentate ligand? With which of its atoms will it…

A: Will methylamine (CH3NH2) be a monodentate or a bidentate ligand? With which of its atoms will it…

Q: About the chelating agents (ligands) classification

A: Here the point 4 is not correct which states that the trivalent chelating agents/ligands have three…

Q: Can the ammonia ligand engage in linkage isomerism?

A: Linkage isomerism is shown by ligands that are similar in their compositions but differ in the atoms…

Q: A complex of nickel ions, Ni2*, with 1,2-diaminoethane is octahedral in shape with a co-ordination…

A: Ni2+ forms an octahedral complex with1,2-diaminoethane (NH2C2H4 -NH2) with coordination 6. Since,…

Q: Determine the symmetry of the orbital groups for the donor sigma bonds (σ) of the ligand in an…

A:

Q: Oxyhemoglobin, with an O2 bound to iron, is a low-spin Fe(II) complex; deoxyhemoglobin, without the…

A: Oxyhemoglobin and deoxyhemoglobin are derivatives of hemoglobin. Both are octahedral complexes. One…

Q: Which of the following statements about 10Dq is false? A. In the [CoX(NH3)5]n+ complex, the color…

A: The energy difference in the coordination compound related to colour.In  Strong field ligand,higher…

Q: Give the molecular orbital diagram for the diatomic fluorine 2- ion, including labels for all…

A: Hey, since there are multiple questions posted, we will answer first question. If you want any…

Q: Explain why there is no distinction between low and high-spin arrangements for an octahedral d8…

A:

Q: Which of the following ligands is ambidentate? Select one or more: a. N3- b. SO42- c. SO32- d. SCN-

A: Ambient ligands : Such ligands have two or more donor atoms but only one donor atom is attached to…

Q: [Mn(H2O)6]?* complex has an extremely pale color, attributable to transitions which are formally…

A:

Q: The (2-aminoethyl)phosphine ligand, acts as a bidentate ligand with metals of Transition. i) How…

A: The structure of (2-aminoethyl)phosphine ligand is

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.