1. Consider the following reductions and arrange them in order of decreasing tendency to occur from the given reactions (or lack of reaction) below: Reductions Reactions IrCl 3- Ir 1. Ir + S -→ No Reaction H2S 2. F2 + Ce³* → CeOH³* + F HCIO2 Cl 3. Ir + HCIO2 → cr + IrCl- F2 F- 4. HC1O2 + Ce* → No Reaction CEOH³* Ce3+ Explain how you arrive at your arrangement. What substance is the strongest reducing agent? What substance is the weakest reducing agent?

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section: Chapter Questions
Problem 20.48P
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1. Consider the following reductions and arrange them in order of decreasing
tendency to occur from the given reactions (or lack of reaction) below:
Reductions
Reactions
IrCl
3-
Ir
1. Ir + S -→ No Reaction
H2S
2. F2 + Ce³* → CeOH³* + F
HCIO2
Cl
3. Ir + HCIO2 → cr + IrCl-
F2
F-
4. HC1O2 + Ce* → No Reaction
CEOH³*
Ce3+
Explain how you arrive at your arrangement.
What substance is the strongest reducing agent?
What substance is the weakest reducing agent?
Transcribed Image Text:1. Consider the following reductions and arrange them in order of decreasing tendency to occur from the given reactions (or lack of reaction) below: Reductions Reactions IrCl 3- Ir 1. Ir + S -→ No Reaction H2S 2. F2 + Ce³* → CeOH³* + F HCIO2 Cl 3. Ir + HCIO2 → cr + IrCl- F2 F- 4. HC1O2 + Ce* → No Reaction CEOH³* Ce3+ Explain how you arrive at your arrangement. What substance is the strongest reducing agent? What substance is the weakest reducing agent?
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