• 1. Draw out the detailed mechanism for the reaction between (CO),Mn-CH, and PPH3 to yield (PPH3)(CO),Mn–(CO)CH3. • 2. Give the electron counts for each organometallic complex in the catalytic cycle for Wilkinson's catalyst (given on the next slide.

• 1. Draw out the detailed mechanism for the reaction between (CO),Mn-CH, and PPH3 to yield (PPH3)(CO),Mn–(CO)CH3. • 2. Give the electron counts for each organometallic complex in the catalytic cycle for Wilkinson's catalyst (given on the next slide.

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter24: Catalytic Carbon-carbon Bond Formation

Section: Chapter Questions

Problem 24.22P

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Question

• 1. Draw out the detailed mechanism for the
reaction between (CO),Mn-CH, and PPH3 to
yield (PPH3)(CO),Mn–(CO)CH3.
• 2. Give the electron counts for each
organometallic complex in the catalytic cycle for
Wilkinson's catalyst (given on the next slide.

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