1.Describe the Re-Re bonding and expected structures for [ReCl4]24- and [ReCl4]22-. 2.Why does K4[NiBr6] behave as a simple Curie paramagnet , but K2 [NiBr4] exhibit complex paramagnetic behavior with a temperature dependent effective magnetic moment .
1.Describe the Re-Re bonding and expected structures for [ReCl4]24- and [ReCl4]22-. 2.Why does K4[NiBr6] behave as a simple Curie paramagnet , but K2 [NiBr4] exhibit complex paramagnetic behavior with a temperature dependent effective magnetic moment .
Chapter12: Spectrochemical Methods
Section: Chapter Questions
Problem 13P
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1.Describe the Re-Re bonding and expected structures for [ReCl4]24- and [ReCl4]22-.
2.Why does K4[NiBr6] behave as a simple Curie paramagnet , but
K2 [NiBr4] exhibit complex paramagnetic behavior with a temperature dependent effective magnetic moment .
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