1.Describe the Re-Re bonding and expected structures for [ReCl4]24-  and  [ReCl4]22-. 2.Why does   K4[NiBr6]  behave as a simple Curie paramagnet , but K2 [NiBr4] exhibit complex paramagnetic behavior with a temperature dependent effective magnetic moment .

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
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Chapter12: Spectrochemical Methods
Section: Chapter Questions
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1.Describe the Re-Re bonding and expected structures for [ReCl4]24-  and  [ReCl4]22-.

2.Why does   K4[NiBr6]  behave as a simple Curie paramagnet , but

K2 [NiBr4] exhibit complex paramagnetic behavior with a temperature dependent effective magnetic moment .   

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