Question

Asked Oct 21, 2019

This problem is (11.3) from a book "Thermodynamics and Statistical Mechanics An Integrated Approach by M. Scott Shell"

Step 1

By helping to the first law of thermodynamic equation 1 is converted in terms of C_{V} and ideal gas law.

After converting equation 1 result equation 2 because enthalpy is the function of f (T, V).

Step 2

Equation 2 multiply by T and get equation 3, in terms of enthalpy at constant volume converted into C_{V}/T sub-equation (a) and first Maxwell relation sub-equation (b). Put in the equation 3.

Found that first TdS relation equation 4.

Step 3

Behalf of third Maxwell relation got that equation 5, arranging the equation in terms of temperature equation 6 write that. ...

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