1A 8A н -73 Не 2A 6A 7A ЗА 5A B Ne Li Be -27 -122 >0 -141-328 >0 -60 Na Mg |-53 >0 Al CI Si Ar -43 -134 -72 -200 -349 >0 K -48 Ca -2 As Se -30 -119 -78 -195-325 >0 Ga Ge Br Kr Sr -5 Rb In Sn Sb Te Xe -30 -107-103–190 -295 >0 -7 A Figure 7.12 Electron affinity in kJ/mol for selected s- and p-block elements.

Chemistry In Focus
7th Edition
ISBN:9781337399692
Author:Tro, Nivaldo J.
Publisher:Tro, Nivaldo J.
Chapter9: Energy For Today
Section: Chapter Questions
Problem 9E
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Question

Group 4A elements have much more negative electron
affinities than their neighbors in groups 3A and 5A (see
Figure 7.12). Which of the following statements best explains
this observation? (i) The group 4A elements have much higher
first ionization energies than their neighbors in groups 3A
and 5A. (ii) The addition of an electron to a group 4A element
leads to a half-filled np3 outer electron configuration.
(iii) The group 4A elements have unusually large atomic radii.
(iv) The group 4A elements are easier to vaporize than are
the group 3A and 5A elements.

1A
8A
н
-73
Не
2A
6A
7A
ЗА
5A
B
Ne
Li
Be
-27 -122 >0
-141-328 >0
-60
Na Mg
|-53 >0
Al
CI
Si
Ar
-43 -134 -72 -200 -349 >0
K
-48
Ca
-2
As
Se
-30 -119 -78 -195-325 >0
Ga
Ge
Br
Kr
Sr
-5
Rb
In
Sn
Sb
Te
Xe
-30 -107-103–190 -295 >0
-7
A Figure 7.12 Electron affinity in kJ/mol for selected s- and p-block elements.
Transcribed Image Text:1A 8A н -73 Не 2A 6A 7A ЗА 5A B Ne Li Be -27 -122 >0 -141-328 >0 -60 Na Mg |-53 >0 Al CI Si Ar -43 -134 -72 -200 -349 >0 K -48 Ca -2 As Se -30 -119 -78 -195-325 >0 Ga Ge Br Kr Sr -5 Rb In Sn Sb Te Xe -30 -107-103–190 -295 >0 -7 A Figure 7.12 Electron affinity in kJ/mol for selected s- and p-block elements.
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