2. Provide all the isomers for the for the following complexes: (a) triammineaquadichlorocobalt(III) chloride (b) Re(arphos)»Brɔ As(CH3)2 arphos = P(CH3)2

Q: What is the formula of the complex cation? + NH3 H3N 'CI NH3 trans-[Co(NH,),CI,] cis-[CoCI,(NH,),I…

A: Which of the given option is correct--

Q: [Cr(H₂O)₆]²⁺ is violet. Another CrL₆ complex is green.Can ligand L be CN⁻? Can it be Cl⁻?…

A: Given: [Cr(H₂O)₆]²⁺

Q: Consider an octahedral complex MA3B3. How many geometric isomers are possible? Will any of the…

A: There are two geometrical isomer of the octahedral complex for MA3B3.

Q: Consider an octahedral complex MA3B3. How many geometric isomers are expected for this compound?…

A: Isomerism-molecules with same molecular formula but different structural formula called as isomers…

Q: [Cr(H2O)6] 2+ is violet. Another CrL6 complex is green. Can ligand L be CN-? Can it be Cl-? Explain.

A: The octahedral splitting energy of transition elements is the difference in the energy of the…

Q: What energy levels are occupied in a complex such ashexacarbonylchromium(0)? Are any electrons…

A: According to the molecular orbital theory, the atomic orbitals combine to form new molecular…

Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1. Linkage…

A: Linkage isomer :-       It is a isomer of coordination compound,  in which ambidentate ligands have…

Q: The compound 1,1,1-trifluoroacetylacetone (tfa- is a bidentate ligand: CF,CC H2CCH3 2+ It forms a…

A:

Q: How many stereoisomers of a hypothetical six-coordinate complex [M(AA);bc] (where AA is a bidentate…

A: Stereoisomers include Geometrical isomers and Optical isomers. There are two Geometrical isomers…

Q: Describe the types of NO bonds by demonstrating the electrons involved. This is an acid (pi) ligand…

A: The metal uses t2g orbital to form pi bonds with ligands. Pi star orbital of metal is high energy…

Q: Which of the following is the double-toothed l

A: Metal (M) :  electron pair acceptor  Ligand (L) : electron pair donar  Metal and ligand can form…

Q: "Are all the organometallic complexes stable to moisture and temperature?" Explain.

A: the thermal stability organometallic compound generally decreases from the lightest to the heaviest…

Q: Explain the following giving an example in each case: (i) Linkage isomerism (ii) An outer orbital…

A:

Q: In the coordination compound (NH4)2[Fe(OH2)F;], the e is octahedrally coordinated. (a) Based on the…

A: a) The given compound is (NH4)2[Fe(OH2)F5] or [Fe(OH2)F5]2-. The oxidation state of Fe is +3 and it…

Q: Explain the following :(i) Low spin octahedral complexes of nickel are not known.(ii) The…

A: Low spin octahedral complexes are formed when the central metal atom undergo d2sp3 hybridisation by…

Q: A four-coordinate complex MA2B2 is prepared and found tohave two different isomers. Is it possible…

A:

Q: coordination isomers

A:

Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1.…

A: The given condition is: Geometric isomers of anionic complexes containing hexacoordinated Os4+ and…

Q: A d' octahedral complex is found to absorb visible light, with the absorption maximum occurring at…

A:

Q: 2. Red crystalline [NiCl,(PPh,CH,Ph)2] is diamagnetic. On heating to 387 K for 2 hours, a blue-…

A: In this complex, nickel is in +2 oxidation state and it has valence shell electronic configuration…

Q: Explain the terms diamagnetic and paramagnetic NiCl2(PPh3)2 is a green paramagnetic solid, while cis…

A: If a compound have unpaired electrons in its orbital, then the compound is known as paramagnetic in…

Q: The acetylacetone ion forms very stable complexes with many metallic ions. It acts as a bidentate…

A: Concept introduction: Ligands that can bind central metal ion from two sites are called bidentate…

Q: By taking into account the following complexes: A) [Co(en):]³* B)[CoCl3Br3]+ a) Give the oxidation…

A: In this question, we have to find out the correct answer of given problem by the help of the…

Q: Draw the structures and give the stock names of complexes that can satisfy the following conditions:…

A:

Q: How many unpaired electrons are in the low-spin octahedral complex [Co(CN),Jª¯? Provide your answer…

A: The no. Of unpaired electron in given complex = 1 (one).

Q: There

A: We will identify same molecule and isomer of 1 molecule

Q: Write the formula and the name of each complex ion- a complexion with Co3+ as the central ion and…

A: (1) a complexion with Co3+ as the central ion and three NH3 molecules and three CN-ions as ligands…

Q: The factor determining the mechanism observed in the substitution reactions of square plane…

A: here, for the nucleophilic substitution reaction Sn2 for the inorganic reaction mechanism  yes, This…

Q: Cis-diamminedichloroplatinum (II) or “cisplatin” is a square planar complex with the formula…

A: The structure of cis-platin and trans-platin is shown as follows: Among Geometrical Isomers,…

Q: Sketch the structures of the following complexes. Indicate any cis, trans, and optical isomers.(a)…

A:

Q: SAIC Ex7.1 Name and draw structures of the following complexes: a) [Ni(CO)4], b) [Ni(CN)4] , v)…

A: a) [Ni(CO)4] -  Tetracarbonylnickel (0)  b) [Ni(CN)4]2- - Tetracyanonickelate (II) ion  c) [CoCl4]2-…

Q: If a solution known to be made up of an octahedral cobalt complex ion [Co(NH3)6]3+ appears orange to…

A: [Co(NH3)6]3+ is an octahedral complex with six ammonia ligands. Cobalt has the atomic number 27,…

Q: (a) Give the name of the following metal complexes based on the latest IUPAC nomenclature. O…

A:

Q: or the following coordination complex (Mn(C204)(H20)2C13} Sive the name diaquatrichloridooxalatomang…

A:

Q: Write the hybridization and shape of the following complexes: (i) [CO(NH3)6]3+ (ii) [NiCl4]2-…

A: Hybridization involves the mixing up of of atomic orbitals into new hybrid orbitals with different…

Q: Write the valence electron configuration for the cobalt ions in the complexes [CoCl4]2- and draw…

A:

Q: 2. It was stated that Co3+ complexes are very stable and the ligands in such complexes are not…

A:

Q: 3. Considering an octahedral complex for the d system,what are the effect of T-donor and t- acceptor…

A: Pi donar Ligands produce lesser splitting energy so high spin will be favored. Pi accepting lingands…

Q: What are the characters for the operations C2, C4, σd, and σv(xz) respectively, on the LCAO Ψ(L1+L3)…

A: Cn is a rotation of (360/n)". C2= 180°rotation, C4= 90°rotation

Q: Can the ammonia ligand engage in linkage isomerism?

A: Linkage isomerism is shown by ligands that are similar in their compositions but differ in the atoms…

Q: In each the following generalized coordination complexes, M represents the central metal ion and L1,…

A: Two compounds that have the same molecular formula but the different structural representation of…

Q: (a) A complex absorbs photons with an energy of4.51 x 10-19 J. What is the wavelength of these…

A: (a)

Q: Given the colors observed for VO43- (orthovanadate ion), CrO42- (chromate ion), and MnO4-…

A: The color of VO43- (orthovanadate ion) is pale yellow. The color of CrO42- (chromate ion) is strong…

Q: Are bipyridines (bipy) and analogous amines, phenanthroline (phen) and terpyridine (terpy) chelate…

A: Yes, bipyridine and analogous amines, phenanthroline and terpyridine are chelate ligands.

Q: Describe the makeup of a complex ion, including the natureof the ligands and their interaction with…

A: Complex molecules are a section of inorganic chemistry . A complex is formed when a metal center is…

Q: What kind of isomerism can the following complexes have? [Cd(NH3)2Cl4]SO4 , and [Mn(H2O)2(NH3)3OH]+

A: The exchange of the ions without changing the identity of a complex molecule is called Ionization…

Q: For each of the following complexe ate) and give its magnetic propertie 3. [Fe(NH,),J²* [Cr(CO),J*

A: Concept is based on spectrochemical series. It decides the spin of ligands.

Q: For any of the following that can exist as isomers, state the type of isomerism and draw the…

A: Two compounds that are similar in terms of molecular formula but distinct from each other in terms…

Q: When Werner's student Edith Humphrey first synthesized the complex complex salts of formula…

A: This is an example of Linkage isomerism of -NO2 ligand.  When a particular ligand is binding to a…

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.