2. Two octahedral complex are shown as below. OCH3 H3CO, OCH3 MeO2C CO,Me Al H3CO OCH3 MeO2C cO,Me ÓCH3 ČO,Me c. Calculate the spin-only magnetic moment of the metal central in each complex.

Q: So I am working with an octahedral complex that has two weak field ligands (Cl) and 4 strong field…

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Q: A complex is found to correspond to the empirical formula (CO)3ReCl. How could it attain the 18 e…

A: 18 electron rule is very much useful for metal complexes .  The structure is square planner .

Q: (a) A complex containing three pyridine and three ammonia ligands bound to a Ni(II) ion was found to…

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Q: 7. Based on the principles learned in class, order the following coordination complexes from the…

A: Inner orbital complexes are form most stable complexes as compare to outer orbital complexes.  Above…

Q: ) Figure 5 shows four energy diagrams, labelled A to D. The diagrams depict possible configurations…

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Q: The complex [Co(ox)(PMe, ),(NH,)C1]shows total number of isomers is ....... A) 5 B) 4 C) 3 D) 2

A: The compounds that have same molecular formula but have different arrangement of atoms in a space…

Q: The complex [Pt(NH3)2(SCN)2] forms two stereoisomerws whereas the complex [Pt(en)(SCN)2] forms only…

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Q: (a) Draw all the possible isomers of [Fe(NH3);Br3] and for each isomer clearly indicate the…

A: a) There are two possible isomers of the given compound, fac and mer. These are shown as below:…

Q: Complex [Co(en):] [Co(CN)} [CoF6] [Co(NH;)6]* [Co(H2O),]*" Ao (cm ) 23,160 33,700 13,100 23,000…

A: 3. a. We have to tell among the given complexes, which two would be best explained by the σ-only…

Q: • Name these coordination complexes: •a. Cr(NH3);Cl3 •b. Pt(en)Cl, • . [Pt(ox),]? а. С.

A: a. Given, Cr(NH3)3Cl3  Name => Triamminetrichloridochromate(III)

Q: The compound 1,1,1-trifluoroacetylacetone (tfa- is a bidentate ligand: CF,CC H2CCH3 2+ It forms a…

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Q: Consider the coordination complex [Cr(OH2)3CI3]Br3 Identify the ligands by name (include the word…

A: Given complex--- [Cr(OH2)3Cl3]Br3

Q: What determine whether a molecule or ion complex is chiral? How would you differentiate between…

A: A chiral is an object that is not identically super-imposable with a mirror image of itself. An…

Q: [FeL6]* complex (L indicates a monodentate ligand) has a magnetic moment of approximately 1.73 B.M.…

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Q: 1_The complex [Co(CN)6]3- does not exhibit Jahn-Teller distortion. Explain  2_[Ni(NH3)4Cl2] does not…

A: Hello. Since the question contains more than three sub-parts, the first three sub-parts shall onl be…

Q: 2. Octahedral complex are shown as below. OCH3 H3CO LOCH3 Al H3CO `OCH3 ÓCH3 a. Calculate the CFSE…

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Q: Determine if each of the following metal complexes is chiral and therefore has an optical isomer:…

A: a.

Q: octahedral complex is found to absorb visible light, with the absorption maximum occurring at 507…

A: The absorption with maximum wavelength by an electron is equal to the energy difference between…

Q: which of these complexes will show geometrical isomerism: a  MA2X2 b  MA2XY c  MABCY d  All of these

A: Geometric isomerism:Two or more compounds with the same formula but are having different…

Q: Which complex ion possesses the largest number of unpaired electrons? 21 23 24 25 26 27 28 29 30 Sc…

A: We have to see the splitting diagram. And nature of ligand to predict the unpaired electron. Strong…

Q: Consider the coordination compound [Pt(NH3)4(OH)2]SO4 and identify ligands ? a. NH3 , OH- O b. OH ,…

A: Ligands in the above coordinated complex are given below

Q: Is this complex [Co(NH3)5Cl]CI2 paramagnetic or diamagnetic, explain?

A: Diamagnetic or paramagnetic nature of compound. If metal contains unpaired electrons then compound…

Q: 2. Sketch and name two geometrical isomers of [Cr(NH3)2(CO)4]2+ () Is this compound paramagnetic or…

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Q: 1. [RhCl3(OH)l 2. [Cr(en)2{PM@3}2!

A: The coordination number of rhodium is 6. The oxidation state of rhodium is +3 d2sp3- hybridization.…

Q: Name the following ligands: A.H2NCH2.CH2NH2 B. NO3 C. NH3 D. Br

A: a) Ethylenediamine b) Nitrato

Q: Sketch the structures of the following complexes. Indicate any cis, trans, and optical isomers.(a)…

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Q: Consider the complex ion [Mn(OH2)612* with 5 unpaired electrons. Which response includes all the…

A: In [Mn(OH2)6]2+  Mn is as Mn2+  Thus d5 octahedral complex.

Q: The total no of electrons that are donated by CN ligands in the following complex is: 2-…

A: Given, [Fe(CO)2(CN)4]2- Total number of electrons that are donated by CN ligands in the following…

Q: For the following transition metal complexes match the complex with its corresponding number of d…

A: The electronic configuration with the corresponding number of d electrons and low spin / high spin…

Q: Depict and explain the Crystal field stabilization theory based on the color the below complexes.…

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Q: Strong Jahn Teller distortion cannot be observed in the following octahedral complexes. A) Cr(II) в)…

A: ⊙ In octahedral complex Strong Jahn Teller distortion occur when 'eg' orbital     orbital…

Q: explain and prove if [Fe(acac)3] is diamagnetic high spin octahedral complex using valence bond…

A: Acac is strong feild ligand, so according to VBT pairing take place and formation inner sphere…

Q: Determine if each of the following metal complexes is chiral and therefore has an optical isomer:…

A: A compound having all different group are said to be chiral. If a carbon is having all four groups…

Q: Complex that obeys the 18-electron rule would be » [(n* -C,H.) Fe(CO),]. B) [[n° -C,H,)Mo(CO), ] c)…

A: All the ligands present in the complex with their electron count for the neutral state are shown…

Q: When a certain weak-field ligand forms an octahedral complex with Coʻ 2+ cation, the energies of the…

A: We have find out the unpaired electrons,  nature and colour of octahedral complex.

Q: Q5. Fill in the following table the correct values for F(CO) in the following complexes ((2055, 2090…

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Q: 15. In 1844, cis- and trans-[PtCl2(NH3)2] were discovered. The FDA approved the anti-cancer drug…

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Q: Formula Geometry around central Charge of Structure Coordination Complex lon Ligands Counter lon CN…

A: The octahedral complexes have coordination number 6. The trigonal bipyramidal complexes have…

Q: In the below coordination compound, the sodium ions are A._______the hydroxide ions are counterions…

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Q: The following neutral molecules or ionic species are considered: CIo, CNO, NH3, O2, CH4,…

A: Coordinate complex is form by the coordinate covalent bond. In coordinate covalent bond the central…

Q: Name the following complex: [Ni(en)2(F)(NO2)][PtCl3(py)]

A: bis(ethylenediamine)flurido(nitrito-N)nickel(III) trichloridopyridineplatinate(II)

Q: 1. The complex ion [Ni(en)2]2+ is… A. is diamagnetic because all electrons are paired B. is…

A: (1) When the complex have unpaired electrons , it is paramagnetic and when the complex have paired…

Q: The type of isomerization in the following complex is 3+ 3- 3+ 3- NH3 NH3 CN NC CN Cr. NC CN CN NH3…

A: Solution :           Coordination compounds  consist of central metal atom or ion surrounded by ions…

Q: The complex Mo(CO)3(NCC2H5)3 has the infrared spectrum shown below. Is this complex more likely the…

A: The mentioned complex is Mo(CO)3(NCC2H5)3

Q: Three complex ions of cobalt(III), [Co(CN),]?-, [Co(NH;),]*, and (CoF, absorb light at wavelengths…

A: The given complex ions are [Co(CN)6]3-, [Co(NH)6]3+ and [CoF6]3- The given wavelengths are  290 nm,…

Q: What was the test that could used to determine the oxalate concentration in this complex?

A: A coordination complex is the result of a Lewis acid-base reaction in which neutral molecules or…

Q: Determine whether the following complexes are low spin or high spin complex (i) [Co(CN)6]* [CoF6]3-…

A: In low spin 3d metal complexes, the electrons are paired in the lowest energy state before filling…

Q: One of the more famous species in coordination chemistry is the Creutz-Taube complex: 5+ (NH3);RuN…

A: (a). There is one metal ion in the complex i.e; Ru. It exhibits two different oxidation states: 1st…

Q: The three complex ions [Mn(CN),]³-, [Mn(CN),J*¯, and [Mn(CN),]³- have all been synthesized and all…

A: All three complexes has cyanide ligand, CN- which is a strong field ligand , thus all complexes are…

Q: The octahedral complex ion [Co(NH3)6]** has fewer unpaired spins than the octahedral complex ion…

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Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.