3) 2.413 g sample contains Na CO̟, NaHCO and inert material. This sample was solved in water and diluted to 250.0 ml. 80 ml solution was taken and titrated with 0.09644 N HCl with the indicator of phenolftalein. 6.13 ml HCl was consumed. From a second solution, again 80 ml was taken and titrated with the same HCl solution with the indicator of methylorange. 15.4 ml HCl was consumed. Calculate the percentage of NaHCO¸ and 3 Na CO in sample (Na CO_=106.0 g/mol, NaHCO_=84.02 g/mol). 3

3) 2.413 g sample contains Na CO̟, NaHCO and inert material. This sample was solved in water and diluted to 250.0 ml. 80 ml solution was taken and titrated with 0.09644 N HCl with the indicator of phenolftalein. 6.13 ml HCl was consumed. From a second solution, again 80 ml was taken and titrated with the same HCl solution with the indicator of methylorange. 15.4 ml HCl was consumed. Calculate the percentage of NaHCO¸ and 3 Na CO in sample (Na CO_=106.0 g/mol, NaHCO_=84.02 g/mol). 3

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter16: Applications Of Neutralization Titrations

Section: Chapter Questions

Problem 16.40QAP

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A 1.200-g sample of a mixture of NaOH (FW 40.00 g/mol) and NayCO3 (FW 105.99 g/mol) with inert impurity is dissolved in 100 mL water and titrated with 0.150 M HCI.With phenolphthalein as the indicator, a 50.00 mL aliquot of the solution turns colorless after the addition of 30.00 mL of the acid. Methyl orange is then added, and 7.00 ml more of the acid are required for the color to change to pink. What is the percentage of NaOH in the sample?
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A pure organic compound has the formula C4H8SOx. A sample of a compound wasdecomposed; the sulfur was converted to sulfate and titrated in a modified version of theadsorption indicator procedure. From the following data, determine the correct formula forthe compound.Given: weight of sample = 12.64 mgBa(ClO4)2 needed for titration = 10.60 mL of 0.0100 M Ba(ClO4)2
For the adjustment of 0.1 M HCl standard solution, 0.1345 g Na2CO3 in primary standard purity was weighed, dissolved in 50 mL of distilled water and titrated with HCl solution. As a result of the titration, 14 mL of acid solution was consumed. Accordingly, what is the true concentration of the HCl solution?
1.0 g of a solid sample known to contain a mixture of NaOH and Na2CO3 is dissolved with distilled water and completed to 25 mL. By adding 2 drops of phenolphthalein (pT = 9.0) to the solution obtained, it was titrated with 0.107 M calibrated HCl solution, and the consumption was determined as 10.6 mL. Subsequently, 2 drops of methyl red (pT = 4.4) were added onto the same solution and titrated, the consumption was determined as 6.1 mL. Accordingly, calculate the amount of NaOH and Na2CO3 in the sample solution as% (a/a) by writing the related reactions. (Na: 23, C: 12, O: 16, H: 1 g / mol)
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In order to adjust the Potassium Permanganate solution, 0.0544g Na2C2O4 was taken and necessary experimental procedures were performed on it and the titrant consumption was found to be 7.9 mL. Accordingly, what is the concentration of KMnO4?
What other factors do you need to consider when assessing feasibility of titration?
During the titration of an HClO4solution with 0.10320M NaOH, a CHEM 3A student,Juan becamedistracted and overshot the endpoint. A fellow student Pedrosuggested that he should record the present volume of NaOH added and titrate the excess with a standard acid solution. If the original sample volume was 25.000mL, the volume of NaOH added was 28.060mL. It took 3.4700 mL of 0.10940 M HCl to back-titrate the NaOH andcalculate the molar concentration of the original HClO4solution.
During the titration of an HClO4 solution with 0.10320 M NaOH, a student, Lovely became distracted and overshot the endpoint. A fellow student Ashley suggested that he should record the present volume of NaOH added and titrate the excess with a standard acid solution. If the original sample volume was 25.000 mL, the volume of NaOH added was 28.060 mL. It took 3.4700 mL of 0.10940 M HCl to back-titrate the NaOH and calculate the molar concentration of the original HClO4
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