3 - Consider the gas phase decomposition of acetic acid at 1200 K. It proceeds via two parallel reactions: CH:COOH - CH: + CO: k = 3.74 s CH:COOH - CH:Co + H:0 k: = 4.65 st (a) What is the maximum percentage yield of the ketene CH:CO at this temperature? (b) What is the concentration of the ketene when the extent of reaction when " is 0.5 (50%)? (c) To favor the second reaction, should you increase or decrease temperature?

Chemistry for Engineering Students
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Author:Lawrence S. Brown, Tom Holme
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Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.58PAE
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3 - Consider the gas phase decomposition of acetic acid at 1200 K. It proceeds via two parallel reactions:
CH:COOH → CH+ + CO: ki = 3.74 s
CH:COOH – CH:co + H2O k2 = 4.65 s'!
(a) What is the maximum percentage yield of the ketene CH:CO at this temperature?
(b) What is the concentration of the ketene when the extent of reaction when is 0.5 (50%)?
(c) To favor the second reaction, should you increase or decrease temperature?
Transcribed Image Text:3 - Consider the gas phase decomposition of acetic acid at 1200 K. It proceeds via two parallel reactions: CH:COOH → CH+ + CO: ki = 3.74 s CH:COOH – CH:co + H2O k2 = 4.65 s'! (a) What is the maximum percentage yield of the ketene CH:CO at this temperature? (b) What is the concentration of the ketene when the extent of reaction when is 0.5 (50%)? (c) To favor the second reaction, should you increase or decrease temperature?
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