3. How many moles of each of the following strong electrolytes are needed to give the same freezing point lowering as 1.2 mol of the nonelectrolyte ethylene glycol in 1 kg of water? a. Nacl b. K3PO4
Q: The freezing point of pure water is 0.0°C. How many grams of ethylene glycol (CH,O2) must be mixed…
A: The expression for determining the mass of solute(ethylene glycol) required is shown below, ∆Tf =…
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A: The volume of benzene = 425 mL. Density of benzene = 0.877 g/mL The mass of the solvent = 425 g/mL…
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A: given,mass of sample of an unknown solute=0.461 gmass of water=10.0 gfreezing point of the solution…
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A: Given: mass of unkown: 3.942 g mass of test tube: 30.665 g voulme of water: 20 mL total mass of…
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A: Freezing point depression = i × m × Kf
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- A compound contains 42.9% C, 2.4% H, 16.6% N, and 38.1% O. The addition of 3.16 g of this compound to 75.0 mL of cyclohexane (d=0.779g/mL) gives a solution with a freezing point at 0.0C. Using Table 10.2, determine the molecular formula of the compound.In terms of Raoults law, distinguish between an ideal liquid-liquid solution and a nonideal liquid-liquid solution. lf a solution is ideal, what is true about Hsoln, T for the solution formation, and the interactive forces within the pure solute and pure solvent as compared to the interactive forces within the solution? Give an example of an ideal solution. Answer the previous two questions for solutions that exhibit either negative or positive deviations from Raoults law.Antifreeze solutions are aqueous solutions of ethylene glycol, C2H6O2(d=1.12g/mL). In Connecticut, cars are winterized by filling radiators with an antifreeze solution that will protect the engine for temperatures as low as -20F. (a) What is the minimum molality of antifreeze solution required? (b) How many milliliters of ethylene glycol need to be added to 250 mL of water to prepare the solution called for in (a)?
- A gaseous solute dissolves in water. The solution process has H=15 kJ. Its solubility at 22C and 6.00 atm is 0.0300 M. Would you expect the solubility to be greater or less at (a) 22C and 1 atm? (a) 18C and 6 atm? (a) 15C and 10 atm? (a) 35C and 3 atm?You dissolve 1.0 mol of urea (H2NCONH2) in 270 g of water. The mole fraction of urea is (a) 3710 3 (b) 0.063 (c) 16 (d) 1.0 and its molality is (a) 1.0 (b) 3.7 (c) 0.063 (d) 0.27Distinguish between a strong electrolyte, a weak electrolyte, and a nonelectrolyte. How can colligative properties be used to distinguish between them? What is the vant Hoff factor? Why is the observed freezing-point depression for electrolyte solutions sometimes less than the calculated value? Is the discrepancy greater for concentrated or dilute solutions?
- You make 20.0 g of a sucrose (C12H22O11) and NaCl mixture and dissolve it in 1.00 kg water. The freezing point of this solution is found to be 0.426C. Assuming ideal behavior, calculate the mass percent composition of the original mixture, and the mole fraction of sucrose in the original mixture.Juice (d=1.0g/mL) from freshly harvested grapes has about 24% sucrose by mass. What is the molality of sucrose, C12H22O11, in the grape juice after 25% (by mass) of the water content has been removed? Assume a volume of 15.0 L.The lattice enthalpy of sodium chloride, H for NaCl(s)Na+(g)+Cl(g) is 787 kJ/mol; the heat of solution in making up 1 M NaCl(aq) is +4.0 kJ/mol. From these data, obtain the sum of the heats of hydration of Na+ and Cl. That is obtain the sum of H values for Na+(g)Na+(aq)Cl(g)Cl(aq) If the heat of hydration of Cl is 338 kJ/mol, what is the heat of hydration of Na+?
- A 12-oz (355-mL) Pepsi contains 38.9 mg caffeine (molar mass = 194.2 g/mol). Assume that the Pepsi, mainly water, has a density of 1.01 g/mL. For such a Pepsi, calculate: (a) its caffeine concentration in ppm; (b) its molarity of caffeine; and (c) the molality of caffeine.From the data presented in Figure 12.11, determine which has the more positive enthalpy of solution: NaCl or NH4Cl. Explain.An aqueous solution containing 0.250 mole of Q, a strong electrolyte, in 5.00 102 g water freezes at 2.79C. What is the vant Hoff factor for Q? The molal freezing-point depression constant for water is 1.86C kg/mol. What is the formula of Q if it is 38.68% chlorine by mass and there are twice as many anions as cations in one formula unit of Q?