4. Calculate the value of ΔSo for the decomposition of POCl3 into its constituent elements, as shown below. 2POCl3(g) → P2(g) + O2(g) + 3Cl2(g)

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Chapter18: Thermodynamics And Equilibrium
Section: Chapter Questions
Problem 18.20QP: Given the following information at 25C, calculate G at 25C for the reaction 2A(g)+B(g)3C(g)...
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4. Calculate the value of ΔSo for the decomposition of POCl3 into its
constituent elements, as shown below. 2POCl3(g) → P2(g) + O2(g) + 3Cl2(g)
5. Calculate the value of ΔSo for the formation of calcium chloride from its
constituent elements, as shown below. Ca(s) + Cl2(g) → CaCl2(s)

Thermodynamic Quantities for Selected Substances at 298.15 K (25°C)
AH°f (kJ/mol) AG°f (kJ/mol) S (J/K-mol)
Substance
Calcium
Ca (s)
CaCh (s)
41.4
-795.8
-748.1
104.6
Caz+ (aq)
226.7
209.2
200.8
Chlorine
Cl2 (g)
Cl- (aq)
222.96
-167.2
-131.2
56.5
Oxygen
02 (g)
205.0
H2O (1)
-285.83
-237.13
69.91
Phosphorus
Р2 (g)
PC3 (g)
РОС13 (3)
144.3
103.7
218.1
-288.1
-269.6
311.7
-542.2
-502.5
325
Sulfur
S (s, rhombic)
SO2(g)
SO3(g)
31.88
-269.9
-300.4
248.5
-395.2
-370.4
256.2
Transcribed Image Text:Thermodynamic Quantities for Selected Substances at 298.15 K (25°C) AH°f (kJ/mol) AG°f (kJ/mol) S (J/K-mol) Substance Calcium Ca (s) CaCh (s) 41.4 -795.8 -748.1 104.6 Caz+ (aq) 226.7 209.2 200.8 Chlorine Cl2 (g) Cl- (aq) 222.96 -167.2 -131.2 56.5 Oxygen 02 (g) 205.0 H2O (1) -285.83 -237.13 69.91 Phosphorus Р2 (g) PC3 (g) РОС13 (3) 144.3 103.7 218.1 -288.1 -269.6 311.7 -542.2 -502.5 325 Sulfur S (s, rhombic) SO2(g) SO3(g) 31.88 -269.9 -300.4 248.5 -395.2 -370.4 256.2
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