4. Rank the order of rates of the following concerted substitutions from fastest to slowest. A D NaOCH3 xs diethyl ether Нас. Нас. CH3 NaOCH3 xs CH3OH CHз CHз Hас Hас o: "Cнз F: в .CH3 -Cн, NaoсH, Нас Нас xs diethyl ether :0. CH3 :CI: (a) A> B> C > D (b) A> C> B > D (d) B> C>A>D (c) B> A> C >D NAOCH3 CH3 CHз xs CH30H Hас Hас (f) D> A>C >B (e) C> A>B> D Cl: CHз Which of the following electrophiles would yield the fastest reaction rate in an SN1 reaction?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter15: Radical Reactions
Section: Chapter Questions
Problem 12E
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rank the order of rates of the following concerted substitutions from fastest to slowest 

4.
Rank the order of rates of the following concerted substitutions from fastest to slowest.
A
D
NaOCH3
xs diethyl ether
Нас.
Нас.
CH3
NaOCH3
xs CH3OH
CHз
CHз
Hас
Hас
o:
"Cнз
F:
в
.CH3
-Cн, NaoсH,
Нас
Нас
xs diethyl ether
:0.
CH3
:CI:
(a)
A> B> C > D
(b)
A> C> B > D
(d) B> C>A>D
(c)
B> A> C >D
NAOCH3
CH3
CHз
xs CH30H
Hас
Hас
(f)
D> A>C >B
(e)
C> A>B> D
Cl:
CHз
Which of the following electrophiles would yield the fastest reaction rate in an SN1 reaction?
Transcribed Image Text:4. Rank the order of rates of the following concerted substitutions from fastest to slowest. A D NaOCH3 xs diethyl ether Нас. Нас. CH3 NaOCH3 xs CH3OH CHз CHз Hас Hас o: "Cнз F: в .CH3 -Cн, NaoсH, Нас Нас xs diethyl ether :0. CH3 :CI: (a) A> B> C > D (b) A> C> B > D (d) B> C>A>D (c) B> A> C >D NAOCH3 CH3 CHз xs CH30H Hас Hас (f) D> A>C >B (e) C> A>B> D Cl: CHз Which of the following electrophiles would yield the fastest reaction rate in an SN1 reaction?
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