4.75 An unknown amount of acid can often be determined byadding an excess of base and then "back-titrating" the excess. A0.3471-g sample of a mixture of oxalic acid, which has two ioniz-able protons, and benzoic acid, which has one, is treated withT00.0 mL of 0.1000 M NaOH. The excess NaOH is titrated with20.00 mL of 0.2000 M HCI. Find the mass % of benzoic acid.ruse infor

The number of protons obtained from the mixture are

Answered: 4.75 An unknown amount of acid can…

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter4: Reactions In Aqueous Solution

Section: Chapter Questions

Problem 33QAP

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Laws passed in some states define a drunk driver as one who drives with a blood alcohol level of 0.10% by mass or higher. The level of alcohol can be determined by titrating blood plasma with potassium dichromate according to the following equation 16H+(aq)+Cr2O72(aq)+C2H5OH(aq)4Cr3+(aq)+2CO2(g)+11H2O Assuming that the only substance that reacts with dichromate in blood plasma is alcohol, is a person legally drunk if 38.94 mL of 0.0723 M potassium dichromate is required to titrate a 50.0-g sample of blood plasma?
4.51 What is the role of an indicator in a titration?
Hydrochloric acid. HCl, with a concentration of 0.100 M can be purchased from chemical supply houses, and this solution can be used to standardize the solution of a base. If titrating 25.00 mL of a sodium hydroxide solution to the equivalence point requires 29.67 mL of 0.100 M HCI, what is the concentration of the base?
A sample of solid calcium hydroxide, Ca(OH)2, is allowed to stand in water until a saturated solution is formed. A titration of 75.00 mL of this solution with 5.00102M HCl requires 36.6 mL of the acid to reach the end point. Ca(OH)2(aq)+2HCl(aq)CaCl2(aq)+2H2O(l) What is the molarity?
How many grams of precipitate are formed if 175 mL of a 0.750 M aluminum sulfate solution and 375 mL of a 1.15 M sodium hydroxide solution are mixed together?
Write a net ionic equation for any precipitation reaction that occurs when 1 M solutions of the following are mixed. (a) copper(II) sulfate and sodium chloride (b) manganese(II) nitrate and ammonium hydroxide (c) silver nitrate and hydrochloric acid (d) nickel(II) sulfate and potassium hydroxide (e) ammonium carbonate and sodium nitrate
A 25-mL sample of 0.50 M NaOH is combined with a 75-mL sample of 0.50 M NaOH. What is the concentration of the resulting NaOH solution?
What volume of a 0.3300-M solution of sodium hydroxide would be required to titrate 15.00 mL of 0.1500 M oxalic acid? C2O4(aq)+2NaOH(aq)Na2C2O4(aq)+2H2O(l)
In most of its ionic compounds, cobalt is either Co(II) or Co(III). One such compound, containing chloride ion and waters of hydration, was analyzed, and the following results were obtained. A 0.256-g sample of the compound was dissolved in water, and excess silver nitrate was added. The silver chloride was filtered, dried, and weighed, and it bad a mass of 0.308 g. A second sample of 0.416 g of the compound was dissolved in water, and an excess of sodium hydroxide was added. The hydroxide salt was filtered and heated in a flame, forming cobalt(III) oxide. The mass of cobalt(III) oxide formed was 0.145 g. a. What is the percent composition, by mass, of the compound? b. Assuming the compound contains one cobalt ion per formula unit, what is the formula? c. Write balanced equations for the three reactions described.
A student tries to determine experimentally the molar mass of aspirin (HAsp). She takes 1.00 g of aspirin, dissolves it in water, and neutralizes it with 17.6 mL of 0.315 M KOH. The equation for the reaction is HAsp(aq)+OH(aq)Asp(aq)+H2OWhat is the molar mass of aspirin?
The concentration of a certain sodium hydroxide solution was determined by using the solution to titrate a sample of potassium hydrogen phthalate (abbreviated as KHP). KHP is an acid with one acidic hydrogen and a molar mass of 204.22 g/mol. In the titration, 34.67 mL of the sodium hydroxide solution was required to react with 0.1082 g KHP. Calculate the molarity of the sodium hydroxide.
Relative solubilities of salts in liquid ammonia can differsignificantly from those in water. Thus, silver bromide issoluble in ammonia, but barium bromide is not (thereverse of the situation in water). Write a balanced equation for the reaction of anammonia solution of barium nitrate with an ammoniasolution of silver bromide. Silver nitrate is soluble inliquid ammonia. What volume of a 0.50 M solution of silver bromidewill react completely with 0.215 L of a 0.076 M solutionof barium nitrate in ammonia? What mass of barium bromide will precipitate fromthe reaction in part (b)?

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