5. Balance the following redox equation using the half-reaction method: MnO41 H2O2 Mn2 O2. (acidic medium) Reduction hatf Mno M Oxidation hatf 20, O2 2t 8H Mn a H202 2 t 4 Hz0 No + 020 2Ht 2/2H5e + MnOy 5(H2 0 2.1 t Mn 4 H20) 22H 2e) ipe + 2 Mna 2 Mn2 8 H,O 5 H2O 50,t + 8 HzO t50, + IOH 2 t lo Ht t2 MnO4- 2 Mn 6. Using the balanced redox equation from question #5, answer the following: A] How many mL of a standard 0.150 M KMnO4 solution are required to react with 0.500 grams of hydrogen peroxide, H2O2? B] A student used 32.47 mL of a 0.150 M potassium permanganate, KMnO4, to react with hydrogen peroxide. How many grams of H2O2 reacted with the KMNO4 solution? T6 H+ t 2 MnOy- 8 H20 t502 + 10 H 2t t 2 Mn 197 T T (

5. Balance the following redox equation using the half-reaction method: MnO41 H2O2 Mn2 O2. (acidic medium) Reduction hatf Mno M Oxidation hatf 20, O2 2t 8H Mn a H202 2 t 4 Hz0 No + 020 2Ht 2/2H5e + MnOy 5(H2 0 2.1 t Mn 4 H20) 22H 2e) ipe + 2 Mna 2 Mn2 8 H,O 5 H2O 50,t + 8 HzO t50, + IOH 2 t lo Ht t2 MnO4- 2 Mn 6. Using the balanced redox equation from question #5, answer the following: A] How many mL of a standard 0.150 M KMnO4 solution are required to react with 0.500 grams of hydrogen peroxide, H2O2? B] A student used 32.47 mL of a 0.150 M potassium permanganate, KMnO4, to react with hydrogen peroxide. How many grams of H2O2 reacted with the KMNO4 solution? T6 H+ t 2 MnOy- 8 H20 t502 + 10 H 2t t 2 Mn 197 T T (

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter18: Electrochemistry

Section: Chapter Questions

Problem 24Q: What is wrong with the following statement: The best concentration cell will consist of the...

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In biological systems, acetate ion is converted to ethyl alcohol in a two-step process: CH3COO(aq)+3H+(aq)+2eCH3CHO(aq)+H2OE=0.581V CH3CHO(aq)+2H+(aq)+2eC2H5OH(aq)E=0.197V (E°' is the standard reduction voltage at 25°C and pH of 7.00.) (a) Calculate G°' for each step and for the overall conversion. (b) Calculate E°' for the overall conversion.
What is wrong with the following statement: The best concentration cell will consist of the substance having the most positive standard reduction potential. What drives a concentration cell to produce a large voltage?
Consider a galvanic cell based on the following half-reactions: a. What is the expected cell potential with all components in their standard states? b. What is the oxidizing agent in the overall cell reaction? c. What substances make up the anode compartment? d. In the standard cell, in which direction do the electrons flow? e. How many electrons are transferred per unit of cell reaction? f. If this cell is set up at 25C with [Fe2+] = 2.00 104 M and [La3+] = 3.00 103 M, what is the expected cell potential?
Consider a concentration cell that has both electrodes made of some metal M. Solution A in one compartment of the cell contains 1.0 M M2+. Solution B in the other cell compartment has a volume of 1.00 L. At the beginning of the experiment 0.0100 mole of M(NO3)2 and 0.0100 mole of Na2SO4 are dissolved in solution B (ignore volume changes), where the reaction M2+(aq)+SO42(aq)MSO4(s) occurs. For this reaction equilibrium is rapidly established, whereupon the cell potential is found to be 0.44 V at 25C. Assume that the process M2++2eM has a standard reduction potential of 0.31 V and that no other redox process occurs in the cell. Calculate the value of Ksp for MSO4(s) at 25C.
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