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Asked Oct 6, 2019

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This problem is (8.17) from a book "Thermodynamics and Statistical Mechanics An Integrated Approach by M. Scott Shell"

Step 1

Where x denotes mole fraction of liquids (1 and 2) in the solution

ʋ_{1}^{* }denotes molar volume of pure 1

ʋ_{2}^{*}denotes molar volume of pure 2

C is constant (volume/mol)

Step 2

From the fundamental thermodynamic relation in terms of Gibbs free energy and use Maxwell relation to find out pressure dependence of chemical potential

For mixture thermodynamic relation is written as follows:

Step 3

From Maxwell relation equati...

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