8.17. Two liquids 1 and 2 arc mixcd, and it is found that the molar volumc of the mixture follows the relation vxix2vz x1x2c and v are the molar volumes of pure 1 where the x terms are mole fractions, and 2, and c is a constant with units of volume per mole. Find expressions for the P dependence of the chemical potentials and in terms of the pure-species properties and the constant c.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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This problem is (8.17) from a book  "Thermodynamics and Statistical Mechanics An Integrated Approach by M. Scott Shell"

8.17. Two liquids 1 and 2 arc mixcd, and it is found that the molar volumc of the
mixture follows the relation
vxix2vz x1x2c
and v are the molar volumes of pure 1
where the x terms are mole fractions,
and 2, and c is a constant with units of volume per mole. Find expressions for
the P dependence of the chemical potentials and in terms of the pure-species
properties and the constant c.
Transcribed Image Text:8.17. Two liquids 1 and 2 arc mixcd, and it is found that the molar volumc of the mixture follows the relation vxix2vz x1x2c and v are the molar volumes of pure 1 where the x terms are mole fractions, and 2, and c is a constant with units of volume per mole. Find expressions for the P dependence of the chemical potentials and in terms of the pure-species properties and the constant c.
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