A 0.630 g sample of the ore is completely dissolved in concentrated HNO3(aq). The mixture is diluted with water to a final volume of 50.00 mL. Assume that all the cobalt in the ore sample is converted to Co (aq). 2+ (aq). a. What is the [Co"] in the solution if the absorbance of a sample of the solution is 0.74? b. Calculate the number of moles of Co"(ag) in the 50.00 mL solution. 2+ C. Calculate the mass percent of Co in the 0.630 g sample of the ore.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter8: Sampling, Standardization, And Calibration
Section: Chapter Questions
Problem 8.12QAP
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Absorbance
Beer-Lambert's Law (Spectrophotometry) #2
To spectrophotometrically determine the mass percent of cobalt in an ore containing cobalt and some inert
materials, solutions with known [Co"] are prepared and the absorbance of each of the solutions is
measured at the wavelength of optimum absorbance. The data are used to create a calibration plot, shown
below.
0.80
0.70-
8 0.60-
0.50-
0.40-
0.30
0.20-
0.10-
++-
0.015
Concentration (M)
A 0.6
g sample of the ore is completely dissolved in concentrated HNO3(aq). The mixture is diluted with
2+
water to a final volume of 50.00 mL. Assume that all the cobalt in the ore sample is converted to Co'(aq).
a. What is the (Co] in the solution if the absorbance of a sample of the solution is 0.74?
b. Calculate the number of moles of CoT(ag) in the 50.00 mL solution.
2+
C. Calculate the mass percent of Co in the 0.630 g sample of the ore.
Transcribed Image Text:Absorbance Beer-Lambert's Law (Spectrophotometry) #2 To spectrophotometrically determine the mass percent of cobalt in an ore containing cobalt and some inert materials, solutions with known [Co"] are prepared and the absorbance of each of the solutions is measured at the wavelength of optimum absorbance. The data are used to create a calibration plot, shown below. 0.80 0.70- 8 0.60- 0.50- 0.40- 0.30 0.20- 0.10- ++- 0.015 Concentration (M) A 0.6 g sample of the ore is completely dissolved in concentrated HNO3(aq). The mixture is diluted with 2+ water to a final volume of 50.00 mL. Assume that all the cobalt in the ore sample is converted to Co'(aq). a. What is the (Co] in the solution if the absorbance of a sample of the solution is 0.74? b. Calculate the number of moles of CoT(ag) in the 50.00 mL solution. 2+ C. Calculate the mass percent of Co in the 0.630 g sample of the ore.
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