A 0.7336-g sample of an alloy that contains copper and zinc is dissolved in 8 M HCl and diluted to 100 mL in a volumetric flask. In one analysis, the zinc (At. Mass = 65.38 g/mol) in a 25.00-mL portion of the solution is precipitated as ZnNH4PO4, and isolated as Zn2P2O7 (FM = 304.70g/mol), yielding 0.1163 g. The copper (At. Mass = 63.55 g/mol) in a separate 25.00-mL portion of the solution is treated to precipitate CuSCN (121.63 g/mol), yielding 0.2383 g. Calculate the %w/w Zn and the %w/w Cu in the sample.
A 0.7336-g sample of an alloy that contains copper and zinc is dissolved in 8 M HCl and diluted to 100 mL in a volumetric flask. In one analysis, the zinc (At. Mass = 65.38 g/mol) in a 25.00-mL portion of the solution is precipitated as ZnNH4PO4, and isolated as Zn2P2O7 (FM = 304.70g/mol), yielding 0.1163 g. The copper (At. Mass = 63.55 g/mol) in a separate 25.00-mL portion of the solution is treated to precipitate CuSCN (121.63 g/mol), yielding 0.2383 g. Calculate the %w/w Zn and the %w/w Cu in the sample.
Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.23QAP
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A 0.7336-g sample of an alloy that contains copper and zinc is dissolved in 8 M HCl and diluted to 100 mL in a volumetric flask. In one analysis, the zinc (At. Mass = 65.38 g/mol) in a 25.00-mL portion of the solution is precipitated as ZnNH4PO4, and isolated as Zn2P2O7 (FM = 304.70g/mol), yielding 0.1163 g. The copper (At. Mass = 63.55 g/mol) in a separate 25.00-mL portion of the solution is treated to precipitate CuSCN (121.63 g/mol), yielding 0.2383 g. Calculate the %w/w Zn and the %w/w Cu in the sample.
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