A 30.0 mL aliquot of 0.300 M H_3 PO_4 is mixed with 90.0 mL of 0.200 M KOH, and the mixture is evaporated. Will the salt that crystallizes out be K_3 PO_4, K_2 HPO_4, or KH_2 PO_4? Show your calculations by using an ICE table (or two or three). H_3 PO_4(aq) + KOH_(aq) rightarrow KH_2 PO_4(aq) + H_2 O (l) The next proton on the H_2 PO_4^- would start to react only when more OH^- was added, over and above the first mole: KH_2 PO_4(aq) + KOH_(aq) rightarrow K_2 HPO_4(aq) + H_2 O (I) The final proton on the HPO_4^2- would start to react only when more OH^- was added, over and above the second mole: K_2 HPO_4(aq) + KOH_(aq) rightarrow K_3 PO_4(aq) + H_2 O (I)

Chemistry: Principles and Reactions
8th Edition
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Author:William L. Masterton, Cecile N. Hurley
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Chapter4: Reactions In Aqueous Solution
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A 30.0 mL aliquot of 0.300 M H_3 PO_4 is mixed with 90.0 mL of 0.200 M KOH, and the mixture is evaporated. Will the salt that crystallizes out be K_3 PO_4, K_2 HPO_4, or KH_2 PO_4? Show your calculations by using an ICE table (or two or three).

H_3 PO_4(aq) + KOH_(aq) rightarrow KH_2 PO_4(aq) + H_2 O (l)

The next proton on the H_2 PO_4^- would start to react only when more OH^- was added, over and above the first mole:

KH_2 PO_4(aq) + KOH_(aq) rightarrow K_2 HPO_4(aq) + H_2 O (I)

The final proton on the HPO_4^2- would start to react only when more OH^- was added, over and above the second mole:

K_2 HPO_4(aq) + KOH_(aq) rightarrow K_3 PO_4(aq) + H_2 O (I)

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