A natural products chemist isolated the sphingolipids shown at the right(alpha-GalCerBf) as the mixture of compounds that differed in their chain lengths. The structures shown, including the branching pattern, were determined NMR.   The table below includes the found high-resolution masses of the three major isomers (negative mode,{M-H}-). Fill in the calcualted masses and the error ppm.

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter28: High-performance Liquid Chromatography
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Problem 28.17QAP: Mass spectrometry is an extremely versatile detection system for GC. However, interfacing an HPLC...
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A natural products chemist isolated the sphingolipids shown at the right(alpha-GalCerBf) as the mixture of compounds that differed in their chain lengths. The structures shown, including the branching pattern, were determined NMR.

 

The table below includes the found high-resolution masses of the three major isomers (negative mode,{M-H}-). Fill in the calcualted masses and the error ppm.  

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