Answered: A protein subunit from an enzyme is…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter12: Solutions

Section: Chapter Questions

Problem 12.79QE

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6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.
The Rast method uses camphor (C10H16O) as a solvent for determining the molar mass of a compound. When 2.50 g of cortisone acetate are dissolved in 50.00 g of camphor (k f =40.0C/m), the freezing point of the mixture is 173.44C; that of pure camphor is 178.40C. What is the molar mass of cortisone acetate?
What is the freezing point and normal boiling point of a solution made by adding 39 mL of acetone, C3H6O, to 225 mL of water? The densities of acetone and water are 0.790 g/cm3 and 1.00 g/cm3, respectively.

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