A solution is prepared by dissolving 40.00 g of NaCl (f.w. = 58.44 g mol–1), a non-volatile solute, in enough water (m.w. = 18.02 g mol–1) to result in exactly 1 L of solution at 25 °C. Assume the density of the solution is that of pure water (dsolution = 1.000 g mL–1). The ebullioscopic constant (Kb) for water is 0.513 °C m–1. The cryoscopic constant (Kf) for water is 1.86 °C m–1. The vapor pressure of pure water is 0.0313 atm. Determine the following: Boiling point of solution (in °C to two decimal places) Freezing point of solution (in °C to two decimal places) Vapor pressure of the solution (in atm to three decimal places) Osmotic pressure (in atm to three decimal places)

Chemistry: An Atoms First Approach
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Author:Steven S. Zumdahl, Susan A. Zumdahl
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Chapter16: Spontaneity, Entropy, And Free Energy
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A solution is prepared by dissolving 40.00 g of NaCl (f.w. = 58.44 g mol–1), a non-volatile solute, in enough water (m.w. = 18.02 g mol–1) to result in exactly 1 L of solution at 25 °C. Assume the density of the solution is that of pure water (dsolution = 1.000 g mL–1).

  • The ebullioscopic constant (Kb) for water is 0.513 °C m–1.
  • The cryoscopic constant (Kf) for water is 1.86 °C m–1.
  • The vapor pressure of pure water is 0.0313 atm.

Determine the following:

  1. Boiling point of solution (in °C to two decimal places)
  2. Freezing point of solution (in °C to two decimal places)
  3. Vapor pressure of the solution (in atm to three decimal places)
  4. Osmotic pressure (in atm to three decimal places)
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