A student wishes to determine the chloride ion concentration in a water sample at 25 °C using a galvanic cell constructed with a graphite electrode and a half-cell of AgCl(s) + e⁻ → Ag(s) + Cl⁻(aq) E°red = 0.2223 V And a copper electrode with 0.500 M Cu²⁺ as the second half cell Cu²⁺(aq) + 2 e⁻ → Cu(s) E°red= 0.337 V The measured cell potential when the water sample was placed into the silver side of the cell was 0.0687 V. What is the standard cell potential for this cell in V?

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter18: Electrochemistry
Section: Chapter Questions
Problem 18.50QE
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A student wishes to determine the chloride ion concentration in a water sample at 25 °C using a galvanic cell constructed with a graphite electrode and a half-cell of AgCl(s) + e⁻ → Ag(s) + Cl⁻(aq) E°red = 0.2223 V And a copper electrode with 0.500 M Cu²⁺ as the second half cell Cu²⁺(aq) + 2 e⁻ → Cu(s) E°red= 0.337 V The measured cell potential when the water sample was placed into the silver side of the cell was 0.0687 V.

What is the standard cell potential for this cell in V?

 

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