A tetrahedral site in a closest-packed lattice is formed by four spheres at the corners of a regular tetrahedron. This is equivalent to placing the spheres at alternate corners of a cube. In such a closest-packed arrangement the spheres are in contact, and if the spheres have a radius r, the diagonal of the face of the cube is 2r. The tetrahedral hole is inside the middle of the cube. Find the length of the body diagonal of this cube and then find the radius of the tetrahedral hole.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter11: Liquids And Solids
Section: Chapter Questions
Problem 11.86QE: The coordination number of uniformly sized spheres in a cubic closest-packing (FCC) array is 12....
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A tetrahedral site in a closest-packed lattice is formed by four spheres at the corners of a regular tetrahedron. This is equivalent to placing the spheres at alternate corners of a cube. In such a closest-packed arrangement the spheres are in contact, and if the spheres have a radius r, the diagonal of the face of the cube is 2r. The tetrahedral hole is inside the middle of the cube. Find the length of the body diagonal of this cube and then find the radius of the tetrahedral hole.

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