An ionic compound, LiN((CH3)3Si)2 is commercially available and can be synthesised by deprotonation of ((CH3)3Si)2NH with C4H9Li. Draw an orbital diagram and a sketch to show the overlap of orbitals that produce the bonding in ((CH3)3Si)2N− anion and predict whether the Si−N−Si bond angle in the ((CH3)3Si)2N− anion is larger than, equal to or smaller than 109.5. explain

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter1: Covalent Bonding And Shapes Of Molecules
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Problem 1.78AP
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An ionic compound, LiN((CH3)3Si)2 is commercially available and can be synthesised by deprotonation of ((CH3)3Si)2NH with C4H9Li. Draw an orbital diagram and a sketch to show the overlap of orbitals that produce the bonding in ((CH3)3Si)2N− anion and predict whether the Si−N−Si bond angle in the ((CH3)3Si)2N− anion is larger than, equal to or smaller than 109.5. explain

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