An ionic compound, LiN((CH3)3Si)2 is commercially available and can be synthesised by deprotonation of ((CH3)3Si)2NH with C4H9Li. Draw an orbital diagram and a sketch to show the overlap of orbitals that produce the bonding in ((CH3)3Si)2N− anion and predict whether the Si−N−Si bond angle in the ((CH3)3Si)2N− anion is larger than, equal to or smaller than 109.5. explain
An ionic compound, LiN((CH3)3Si)2 is commercially available and can be synthesised by deprotonation of ((CH3)3Si)2NH with C4H9Li. Draw an orbital diagram and a sketch to show the overlap of orbitals that produce the bonding in ((CH3)3Si)2N− anion and predict whether the Si−N−Si bond angle in the ((CH3)3Si)2N− anion is larger than, equal to or smaller than 109.5. explain
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter1: Covalent Bonding And Shapes Of Molecules
Section: Chapter Questions
Problem 1.78AP
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An ionic compound, LiN((CH3)3Si)2 is commercially available and can be synthesised by deprotonation of ((CH3)3Si)2NH with C4H9Li. Draw an orbital diagram and a sketch to show the overlap of orbitals that produce the bonding in ((CH3)3Si)2N− anion and predict whether the Si−N−Si bond angle in the ((CH3)3Si)2N− anion is larger than, equal to or smaller than 109.5. explain
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