At 25 °C, kr = 1.55 dm6 mol−2 min−1 at an ionic strength of 0.0241 for a reaction in which the rate-determining step involves the encounter of two singly charged cations. Use the Debye–Hückel limiting law to estimate the rate constant at zero ionic strength.

At 25 °C, kr = 1.55 dm6 mol−2 min−1 at an ionic strength of 0.0241 for a reaction in which the rate-determining step involves the encounter of two singly charged cations. Use the Debye–Hückel limiting law to estimate the rate constant at zero ionic strength.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter20: Kinetics

Section: Chapter Questions

Problem 20.91E: What are the rate laws of mechanisms 1 and 2 for oscillating reactions if the second reactions were...

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Question

At 25 °C, k_r = 1.55 dm⁶ mol⁻² min⁻¹ at an ionic strength of 0.0241 for a reaction in which the rate-determining step involves the encounter of two singly charged cations. Use the Debye–Hückel limiting law to estimate the rate constant at zero ionic strength.

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