Bubble point pressure (T and x; are known): 1. Calculate vapor pressures of pure components from Antoine Equations. 2. Calculate the bubble point pressure using Equation 10 (P = E¡ x¿P?"aP). %3D vap. 3. Determine the composition of the vapor phase from Equation 5 (y¡P = x;P;"aP). Еxample 1: Estimate the bubble point pressure of a liquid mixture of 20 mol% n-butane (1), 25% n- pentane (2), 35% n-hexane (3), and 20% n-heptane (4) at 290K. Also calculate the composition of the first bubble of vapor.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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Bubble point pressure (T and x; are known):
1. Calculate vapor pressures of pure components from Antoine Equations.
vap
2. Calculate the bubble point pressure using Equation 10 (P
vap
3. Determine the composition of the vapor phase from Equation 5 (y;P = x;P;uP).
Еxample 1:
Estimate the bubble point pressure of a liquid mixture of 20 mol% n-butane (1), 25% n-
pentane (2), 35% n-hexane (3), and 20% n-heptane (4) at 290K. Also calculate the
composition of the first bubble of vapor.
Transcribed Image Text:Bubble point pressure (T and x; are known): 1. Calculate vapor pressures of pure components from Antoine Equations. vap 2. Calculate the bubble point pressure using Equation 10 (P vap 3. Determine the composition of the vapor phase from Equation 5 (y;P = x;P;uP). Еxample 1: Estimate the bubble point pressure of a liquid mixture of 20 mol% n-butane (1), 25% n- pentane (2), 35% n-hexane (3), and 20% n-heptane (4) at 290K. Also calculate the composition of the first bubble of vapor.
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